Journal ArticleDOI
The Preparation, Characterization, and Catalytic Behavior of MoVTeNbO Catalysts Prepared by Hydrothermal Synthesis
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In this article, a number of MoVTeNbO catalysts with several Mo/Te/V/Nb (1/0.15-0.9) contents have been prepared by hydrothermal synthesis and tested in the selective oxidation of propane and propene to acrylic acid.About:
This article is published in Journal of Catalysis.The article was published on 2002-07-25. It has received 163 citations till now. The article focuses on the topics: Propene & Acrylic acid.read more
Citations
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Journal ArticleDOI
Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?
TL;DR: This Review documents some examples of recent innovations in the field of catalytic selective oxidation from an industrial point of view, highlighting innovative aspects for a better sustainability of the chemical industry.
Journal ArticleDOI
Selective oxidative dehydrogenation of ethane on MoVTeNbO mixed metal oxide catalysts
P. Botella,E. García-González,Ana Dejoz,J.M. López Nieto,M.I. Vázquez,José M. González-Calbet +5 more
TL;DR: In this article, the authors show that MoVTeNbO catalysts are active and highly selective in the ODH of ethane, especially those with a MoVTeNb molar ratio of 1.15-0.17 and heat-treated at 600-650°C.
Journal ArticleDOI
Aerobic Oxidations of Light Alkanes over Solid Metal Oxide Catalysts
TL;DR: This review outlines the properties of supported metal oxides, mixed-metal oxides and zeolites and detail their most common applications as catalysts for partial oxidations of light alkanes to form olefins and oxygenates and identifies common themes in reaction mechanisms and research strategies.
Journal ArticleDOI
Surface chemistry of phase-pure M1 MoVTeNb oxide during operation in selective oxidation of propane to acrylic acid
Michael Hävecker,Sabine Wrabetz,Jutta Kröhnert,Lenard-Istvan Csepei,Raoul Naumann d'Alnoncourt,Yuri V. Kolen’ko,Frank Girgsdies,Robert Schlögl,Annette Trunschke +8 more
TL;DR: In this article, the surface of a highly crystalline MoVTeNb oxide catalyst for selective oxidation of propane to acrylic acid composed of the M1 phase has been studied by infrared spectroscopy, microcalorimetry, and in-situ photoelectron spectrography.
Journal ArticleDOI
Crystalline MoVO based complex oxides as selective oxidation catalysts of propane
TL;DR: In this paper, three single crystalline Mo V O based oxides were synthesized by hydrothermal method and their catalytic performance in the selective oxidation of propane to acrylic acid were compared in order to elucidate the roles of constituent elements and crystal structure in the course of the propane oxidation.
References
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Journal ArticleDOI
Oxidative dyhydrogenation of short chain alkanes on supported vanadium oxide catalysts
T. Blasco,J.M. López Nieto +1 more
TL;DR: In this article, the main data appeared in the last years on the oxidative dehydrogenation (ODH) of short chain alkanes on supported vanadium oxide catalysts, and it was concluded that tetrahedral V5+-species are active and selective sites in the ODH of C2-C4 alkanes.
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Key Aspects of Catalyst Design for the Selective Oxidation of Paraffins
TL;DR: In this paper, a review examines some aspects in the development of heterogenous catalysts for the oxyfunctionalization of light paraffins, focusing on the reaction of paraffin oxydehydrogenation to olefins and n-butane oxidation to maleic anhydride.
Journal ArticleDOI
The oxidative dehydrogenation of ethane over catalysts containing mixed oxides of molybdenum and vanadium
TL;DR: Mixed oxide catalysts, containing molybdenum and vanadium (MoV) together with another transition metal oxide (Ti, Cr, Mn, Fe, Co, Ni, Nb, Ta, or Ce), are active as low as 200 °C for the oxydehydrogenation of ethane to ethylene.
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Selective oxidation of propane to acrylic acid with molecular oxygen
TL;DR: In this article, a review of the state of the art in the selective oxidation of propane to acrylic acid with molecular oxygen is presented. And the current commercial manufacturing process of acrylic acid, as well as the possible oxidation pathways of the propane are included as background information.
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Recent topics of research and development of catalysis by niobium and tantalum oxides
TL;DR: In this article, the current topics of catalysts containing niobium and tantalum, especially in the field of solid acid catalysis and selective oxidation of hydrocarbons are reviewed.