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Journal ArticleDOI

The reduction of chromite in the presence of silica flux

Peter Weber, +1 more
- 01 Mar 2006 - 
- Vol. 19, Iss: 3, pp 318-324
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TLDR
In this article, the mechanism and kinetics of the carbothermic reduction of a natural chromite was studied at 1300-1500°C in the presence of silica, and a two stage reduction mechanism was established.
About
This article is published in Minerals Engineering.The article was published on 2006-03-01. It has received 38 citations till now. The article focuses on the topics: Chromium & Arrhenius equation.

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Citations
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Dissertation

Unique challenges of clay binders in a pelletised chromite pre–reduction process : a case study

TL;DR: In this paper, the unique process considerations of clay binders in this process are highlighted and demonstrated using two case study clays, and it is demonstrated that the clay binder has to impart high compressive and abrasion resistance strengths to the cured pellets in both oxidising and reducing environments (corresponding to the oxidised outer layer and pre-reduced core of industrially produced pellets).
Journal ArticleDOI

Why is CaCO3 not used as an additive in the pelletised chromite pre-reduction process?

TL;DR: In this paper, the effect of CaCO3 addition on pelletised chromite pre-reduction is presented, and it was shown that CaCO 3 addition caused severe decreases in both compressive and abrasion strengths of prereduced pellets, which is unlikely to be negated by mitigation measures.
Journal ArticleDOI

A cleaner method for preparation of chromium oxide from chromite

TL;DR: In this article, a new leaching process for preparing chromium oxide from chromite was studied, using Cr(VI) extracted from the remediation treatment of chromite ore processing residue (COPR) as an oxidant.
Journal ArticleDOI

Unique challenges of clay binders in a pelletised chromite pre-reduction process.

TL;DR: In this article, the unique process considerations of clay binders in this process are highlighted and demonstrated using two case study clays and demonstrated that the clay binder has to impart high compressive and abrasion resistance strengths to the cured pellets in both oxidising and reducing environments (corresponding to the oxidised outer layer and pre-reduced core of industrially produced pellets).
Journal ArticleDOI

The Effect of Carbonaceous Reductant Selection on Chromite Pre-reduction

TL;DR: In this paper, the effects of carbonaceous reductant selection on chromite pre-reduction and cured pellet strength were investigated, and the results indicated that hydrogen (H)- (24% and volatile content (45.8%) were the most significant contributors for predicting variance in prereduction, respectively.
References
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Journal ArticleDOI

The reduction mechanism of a natural chromite at 1416 °C

TL;DR: In this paper, the behavior of a natural chromite from the Bushveld Complex, Transvaal, South Africa, during reduction at 1416 °C by graphite was studied by means of thermogravimetric analysis, X-ray diffraction (XRD) analysis, energy-dispersive Xray analysis (EDAX), and metallographic analysis.
Journal ArticleDOI

Kinetics of the reduction of bushveld complex chromite ore at 1416 °C

TL;DR: In this article, a generalized rate model based on an ionic diffusion mechanism was developed to satisfactorily describe the solid-state carbothermic reduction of chromite, which included the contribution of the interfacial area between partially reduced and unreduced zones in chromite particles and diffusion.
Journal ArticleDOI

The reduction mechanism of chromite in the presence of a silica flux

TL;DR: The reduction behavior of a natural chromite from the Bushveld Complex of South Africa was studied at 1300 °C to 1500 °C in this paper, where graphite was reduced by graphite in the presence of silica.
Journal ArticleDOI

Rate of reduction of Cr2O3 by carbon and carbon dissolved in liquid iron alloys

TL;DR: In this article, the rate of reduction of dense Cr2O3 on the surface of Fe-Cr-C alloys was controlled by diffusion of carbon to surface of the melt, and the chemical diffusion coefficient derived from the results (8.5 × 10-5 cm2/s) is in agreement with previous work.
Journal ArticleDOI

An examination of the decrease of surface-activity method of measuring self-diffusion coefficients in wustite and cobaltous oxide

TL;DR: In this paper, self-diffusion coefficients have been measured for iron in wustite (700° to 1000°C) and for cobalt in cobaltous oxide (800° to 1350°C).
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