Journal ArticleDOI
The Stereochemistry of Complex Inorganic Compounds. XXII. Stereospecific Effects in Complex Ions1
E. J. Corey,John C. Bailar +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1959-06-01. It has received 368 citations till now.read more
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Journal ArticleDOI
Selectivity in propene polymerization with metallocene catalysts.
Journal ArticleDOI
Lanthanide complexes as chiral probes exploiting circularly polarized luminescence
TL;DR: Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light and the design criteria for developing such probes are defined, based on a rigorous stereochemical analysis.
Journal ArticleDOI
Conformational and Coordination Equilibria on DOTA Complexes of Lanthanide Metal Ions in Aqueous Solution Studied by 1H-NMR Spectroscopy
Silvio Aime,Mauro Botta,Mauro Fasano,M. Paula M. Marques,Carlos F. G. C. Geraldes,Dirk Pubanz,Andre E. Merbach +6 more
TL;DR: A variable-temperature, -pressure, and -ionic strength (1)H NMR study of the DOTA complexes of different trivalent cations yielded data that are in contradiction with the hitherto used model of only two enantiomeric pairs of diastereoisomers that differ in the ligand conformations.
Journal ArticleDOI
Computing chiroptical properties with first-principles theoretical methods: background and illustrative examples.
TL;DR: This "tutorial style" review outlines the theoretical foundation for computations of chiroptical properties for optically active molecules and highlights the strengths and weaknesses of currently popular time-dependent density functional methods.
Book ChapterDOI
Crystal structures of metal-peptide complexes.
TL;DR: This chapter illustrates that, the existence of cis-trans isomers coordination isomers, optical isomer, and dimeric species in the crystalline complexes emphasizes the variety of species, which must be considered when equations are written to represent metal–peptide equilibria in solution.