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The sulfenylation of the active methylene compounds by the use of sulfenamides

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This article is published in Tetrahedron Letters.The article was published on 1970-01-01. It has received 27 citations till now. The article focuses on the topics: Methylene.

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Explorations into new reaction chemistry.

TL;DR: The basic concepts that have guided the exploration of new chemical reactions by giving examples of results from my research group are described, and it can be said that by reviewing what the authors had done before, they were able to expand on it to achieve new outcomes.
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Synthesis of disulfides via sulfenylation of alkyl and aryldithiopyridine n-oxides

TL;DR: Alkyl and aryldithiopyridine N-oxides were prepared by the reaction of 2,2′-dithiopyridine-1,1′- dioxide with various thiols in high yields as discussed by the authors.
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Sulfenylation of β-Diketones Using C-H Functionalization Strategy.

TL;DR: The sulfenylation of β-diketones without deacylation under metal-free conditions at ambient temperature via a cross dehydrogenative coupling (CDC) strategy is reported and the resultant products can be further manipulated to form α,α-disubstituted β- dikets and pyrazoles.
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Carbon tetrabromide-mediated carbon-sulfur bond formation via a sulfenyl bromide intermediate.

TL;DR: In the presence of carbon tetrabromide, a variety of dithiocarbamates, xanthates, dithioesters, and thioethers were prepared in one pot by reacting the correspondingdithioic acids or thiols with active methylene compounds/indole derivatives under mild conditions.
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The Reactions of Phosphonium Ylides and Oxosulfonium Methylide with Sulfenamide Derivatives

TL;DR: In this paper, it was found that vinyl sulfide derivatives were obtained in good yields by the reactions of carbonyl compounds with α-phenylthioalkylidenetriphenylphosphorane.
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