Journal ArticleDOI
The unusually robust phosphorus-hydrogen bond in the novel cation [cyclic] HP(NMeCH2CH2)3N+
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This article is published in Journal of the American Chemical Society.The article was published on 1989-04-01. It has received 104 citations till now. The article focuses on the topics: Chemical bond & Hydrogen bond.read more
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Main group atranes: chemical and structural features
TL;DR: A review of chemical reactivities and structural properties of main group atrane systems are surveyed in this paper, where the bridgehead-bridgehead bond length lies between the sum of the van der Waals radii and a normal transannular bond.
Journal ArticleDOI
Carbon Dioxide Reduction to Methylamines under Metal-Free Conditions†
TL;DR: The first metal-free catalysts are reported for the methylation of amines with carbon dioxide, and the new methodology enables themethylation of N-H bonds in a wide variety ofAmines, including secondary amines, with increased chemoselectivity.
Journal ArticleDOI
Azaphosphatranes as Structurally Tunable Organocatalysts for Carbonate Synthesis from CO2 and Epoxides
Bastien Chatelet,Lionel Joucla,Jean-Pierre Dutasta,Alexandre Martinez,Kai C. Szeto,Véronique Dufaud +5 more
TL;DR: Three azaphosphatranes were used as organocatalysts for the synthesis of cyclic carbonates from CO2 and epoxides and proved to be efficient single-component, metal-free catalysts, displaying high stability and productivity over several days of reaction.
Related Papers (5)
The "anomalous" basicity of P(NHCH2CH2)3N relative to P(NMeCH2CH2)3N and p(NBzCH2CH2)3N: a chemical consequence of orbital charge balance?
M. A. H. Laramay,John G. Verkade +1 more