Journal ArticleDOI
Thermal behavior of the saccharinates of K+, Na+, Rb+, Cs+ and NH4+: structural inferences
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TLDR
In this paper, four alkali saccharinates: K 3 (sac) 3 ·2H 2 O (KSac), Rb 2(sac) 2 ·H 2O (RbSac), ammonium saccharinate (AmmSac), Cs(Hsac)(sac)·H2O (CsSac)) and CsSac were synthesized and their thermal decomposition was investigated in the temperature interval 293-873 K by means of thermogravimetric methods (TG, DTG, DTA) in static atmosphere of helium andAbout:
This article is published in Thermochimica Acta.The article was published on 2000-08-28. It has received 17 citations till now. The article focuses on the topics: Thermal decomposition.read more
Citations
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Metal complexes of saccharin
TL;DR: In this paper, a wide variety of metal species based on mononuclear, binuclear, polynuclear complexes and extended coordination polymers are discussed in relation to the coordination modes of the anion, i.e., monodentate (through the N-atom or the carbonylic O-atom), bidentate, tridentate or bridge forming.
Journal ArticleDOI
Supramolecular chemistry and crystal engineering
TL;DR: In this paper, the authors trace the evolution of supramolecular chemistry and crystal engineering starting from the early nineties and projects a center stage for chemistry in the natural sciences.
Journal ArticleDOI
Structural studies of the system Na(saccharinate)n H2O: a model for crystallization.
TL;DR: Not far from a crystal nucleus?
Journal ArticleDOI
Thermal decomposition of triethanolamine and monoethanolethylenediamine complexes of some transition metal saccharinates
TL;DR: The thermal decomposition behavior of triethanolamine (TEA) and monoethanolethylenediamine (me-en) complexes was studied under non-isothermal conditions by TG, DTA and DTG in dynamic nitrogen atmosphere as discussed by the authors.
Journal ArticleDOI
Spectra–structure correlations in solid metal saccharinates. I. The carbonyl stretchings
P Naumov,G Jovanovski +1 more
TL;DR: In this paper, a literature survey of the infrared carbonyl stretching bands of 73 solid saccharinates, saccharin and the saccharini nitranion (the latter in diluted DMSO solution) is presented.
References
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The OH and O-D stretching vibrations in the hydrates of sodium and potassium saccharinate : spectra-structure correlations
TL;DR: The infrared spectra of the two hydrates of sodium saccharinate in the region of the OH and O-D stretching vibrations of protiated and partially deuterated samples are considerably different.
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The thermal decomposition of the pyridine saccharinates of Co, Ni and Cu: A correlation of the structural and the infrared data
TL;DR: In this article, the thermal properties of pyridine saccharinates were investigated in static air and anoxidizing atmosphere, and the decomposition pathways and the stability of the compounds were interpreted in terms of the structural data.
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Coordination compounds of biological interest: Thermal properties of some compounds of saccharin (o-benzoic sulphimide) with nickel(II) and zinc(II)
TL;DR: In this article, the thermal properties of saccharin (sacc) complexes of obenzoic sulphimide have been studied and compared both with those of cobalt(II) and copper (II) previously studied and with ternary complexes of nickel(II), zinc(II, and pyridine as ligands.
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