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Treatment of phosphogypsum waste using suitable organic extractants

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TLDR
The reduction in concentration of radionuclides from PG was investigated and using the desired organic extractant under optimum conditions for treatment of the PG waste leads to obtain a decontaminated product that can be safely used in many industrial applications.
Abstract
Phosphogypsum (PG) is a residue of the phosphate fertilizer industry that has relatively high concentrations of harmful radioactive materials. The reduction in concentration of the radionuclides from PG was investigated. The removal process is based on leaching of radionuclides using suitable organic extractants. The studied radionuclides were 226Ra, 210Pb, 238U and 40K. The factors affect the leaching process such as type of leaching materials, contact time, concentration of the desired solvent, liquid to solid ratio, and temperature were studied. Based on the experimental results, about 71.1, 76.4, 62.4, and 75.7% of 226Ra, 210Pb, 238U and 40K respectively were successfully removed from the PG. The reduction in the concentration of radionuclides was accompanied by reduction in the concentration of rare earth elements (∑REE) equals to 69.8%. Using the desired organic extractant under optimum conditions for treatment of the PG waste leads to obtain a decontaminated product that can be safely used in many industrial applications.

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Journal ArticleDOI

Towards zero-waste valorisation of rare-earth-containing industrial process residues: a critical review

TL;DR: In this paper, the authors discuss the possibilities to recover rare earths from industrial waste streams, which contain only low concentrations of rare-earth elements, but are available in very large volumes and could provide significant amounts of rare Earths.
Journal ArticleDOI

Phosphogypsum as a construction material

TL;DR: In this article, a review of the earlier studies which reused PG as a construction material has been conducted and the effect of PG on some properties of the matrix such as workability, unit weight, mechanical strength and durability has been reviewed and discussed.
Journal ArticleDOI

The story of rare earth elements (REEs): Occurrences, global distribution, genesis, geology, mineralogy and global production

TL;DR: In this article, rare earth (REE) deposits are classified on the basis of their genetic associations, mineralogy and form of occurrences, and their genesis, chronology and mineralogy are discussed.
Journal ArticleDOI

Recovery of rare earth elements from phosphate rock by hydrometallurgical processes - A critical review

TL;DR: In this paper, an overview of achievements aiming at solving the challenges of rare earth elements (REE) recovery from phosphate rock is given, and recommendations to promote the development of REE recovery technologies from phosphate rocks are provided.
Journal ArticleDOI

Phosphogypsum: potential uses and problems – a review

TL;DR: The concentrations of these elements vary between the regions and the processes used, all of which require particular and specific follow-up after the release of PG and during its use.
References
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Book

Perry's Chemical Engineers' Handbook

TL;DR: In this paper, conversion factors and mathematical symbols are used to describe conversion factors in physical and chemical data and Mathematical Symbols are used for converting, converting, and utilising conversion factors.

Perrys chemical engineers handbook

TL;DR: Perry's Chemical Engineers' Handbook as mentioned in this paper is a free download pdf for chemical engineering applications, from the fundamentals to details on computer applications and control, and it can be found in any computer science course.
Book

Chemical Engineers' Handbook

TL;DR: The Chemical Engineers handbook as mentioned in this paper, Chemical engineers handbook, Chemical engineer handbook, Chemical engineers Handbook, Chemical Engineering handbook and Chemical Engineers Handbook, 2007.2.1.
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