Journal ArticleDOI
Tridentate Carbene CCC and CNC Pincer Palladium(II) Complexes: Structure, Fluxionality, and Catalytic Activity
TLDR
In this paper, it was shown that air and thermally stable palladium(II) complexes of CNC and CCC bis-carbene pincer ligands have a twisted conformation and catalyze Heck olefination of activated aryl chlorides.About:
This article is published in Organometallics.The article was published on 2001-11-10. It has received 286 citations till now. The article focuses on the topics: Palladium & Pincer movement.read more
Citations
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Journal ArticleDOI
Heterocyclic Carbenes: Synthesis and Coordination Chemistry
TL;DR: New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclized isocyanides have been developed recently.
Journal ArticleDOI
Cyclometalated phosphine-based pincer complexes: Mechanistic insight in catalysis, coordination, and bond activation
Journal ArticleDOI
Recent homogeneous catalytic applications of chelate and pincer N-heterocyclic carbenes
Eduardo Peris,Robert H. Crabtree +1 more
TL;DR: In this paper, the use of N-heterocyclic carbene ligands (NHCs) based on imidazolium ions and related heterocycles has emerged as an alternative to phosphines in the design of new organometallic catalysts.
Journal ArticleDOI
Dehydrogenation and related reactions catalyzed by iridium pincer complexes
TL;DR: McDonald et al. as mentioned in this paper proposed a method to solve the problem of protein synthesis in the context of the 239th American Chemical Society (ACS) National Meeting of Organometallics 2010.
References
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Journal ArticleDOI
A stable crystalline carbene
TL;DR: Synthese, structure et caracterisation du (1,3-bis [1-adamantyl]-2, 3-dihydro)-2,carbenoimidazole prepare par deprotonation du chlorure de (1 3-bis] [1]- imidazolium as discussed by the authors.
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The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts
TL;DR: In this article, the crystal structure of Ru complex 5, bearing a 1,3dimesityl-4,5-dihydroimidazol-2-ylidene and styrenyl ether ligand is disclosed.
Journal ArticleDOI
Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts
Martin Albrecht,Gerard van Koten +1 more
TL;DR: This review discusses the synthetic methodologies that are currently available for the preparation of platinum group metal complexes containing pincer ligands and especially emphasizes different applications that have been realized in materials science such as the development and engineering of sensors, switches, and catalysts.
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Metal Insertion into C−C Bonds in Solution
Boris Rybtchinski,David Milstein +1 more
TL;DR: A systematic look at the available data on C-C bond activation in solution provides some answers to questions about the ligated metal center and the possible mechanisms of C- C bondactivation in various reaction systems.