Journal ArticleDOI
Two‐Dimensional MXene as a Nanofluidic Anolyte Additive for Enhancing Performance of Vanadium Redox Flow Batteries
Ali Vala Mizrak,Jonathan C. Ehring,Mikhail Shekhirev,Robert W. Lord,Bilen Aküzüm,Pushpendra Singh,Yury Gogotsi,Emin Caglan Kumbur +7 more
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TLDR
In this article , a nanofluidic anolyte additive was used in vanadium redox flow batteries to improve the sluggish kinetics of V2+/V3+ redox reaction.Abstract:
In this work, Ti3C2Tx MXene was investigated as a nanofluidic anolyte additive in vanadium redox flow batteries to improve the sluggish kinetics of V2+/V3+ redox reaction. Numerous electrochemical tests under flow and static conditions were performed to demonstrate the effectiveness of MXenes for VRFB applications. Pressure drop tests and morphology analysis were also conducted to better understand the hydraulic effects of MXene addition into the anolyte. The nanofluidic anolytes with the concentration of 0.10 and 0.15 wt% showed the best electrochemical performance, although the former induced less aggravated hydraulic effects within a reasonable pressure drop range. At a current density of 200 mA cm−2, the nanofluidic analyte containing 0.10 wt% MXene was able to utilize 67 % of the theoretical capacity. Contrarily, with the pristine anolyte, only 10 % of the theoretical capacity could be utilized due to excessive losses. Moreover, the energy efficiency up to 74 % is observed for the nanofluidic electrolyte, which is an increase of 25 % compared to the pristine anolyte. Primarily, the enhanced battery performance was attributed to the improved electrocatalytic activity towards the anodic V2+/V3+ redox reaction. Furthermore, a dynamic, web-like, flowing electrode network is shown to increase the mass transport capacity of porous carbon felt electrodes by creating additional, abundant, and electrochemically active surfaces within the pores. read more
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Minireview on Fluid Manipulation Techniques for the Synthesis and Energy Applications of Two-Dimensional MXenes: Advances, Challenges, and Perspectives
TL;DR: In this paper , a review of the relationship between MXenes and fluid manipulation technique nanofluidics in the domain of energy research is presented, with an emphasis on the applications of MXene-based fluidic techniques in the field of energy harvesting and storage.
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Journal ArticleDOI
2D metal carbides and nitrides (MXenes) for energy storage
TL;DR: More than twenty 2D carbides, nitrides and carbonitrides of transition metals (MXenes) have been synthesized and studied, and dozens more predicted to exist.
Journal ArticleDOI
A review on applications and challenges of nanofluids
TL;DR: It has been found nan ofluids have a much higher and strongly temperature-dependent thermal conductivity at very low particle concentrations than conventional fluids, which can be considered as one of the key parameters for enhanced performances for many of the applications of nanofluids.
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New All‐Vanadium Redox Flow Cell
TL;DR: In this article, a laboratory-scale cell was constructed to test the performance of V(II)/V(III) and V(IV/V(V) half-cells in an all-vanadium redox battery.
Journal ArticleDOI
Semi‐Solid Lithium Rechargeable Flow Battery
Mihai Duduta,Bryan Y. Ho,Vanessa Wood,Pimpa Limthongkul,Victor E. Brunini,W. Craig Carter,Yet-Ming Chiang +6 more
TL;DR: Semi-solid fl ow cells (SSFC) as discussed by the authors is a new storage concept, which combines the high energy density of rechargeable batteries with the fl exible and scalable architecture of fuel cells and fl ow batteries.
Journal ArticleDOI
All-MXene (2D titanium carbide) solid-state microsupercapacitors for on-chip energy storage
You-Yu Peng,You-Yu Peng,Bilen Akuzum,Narendra Kurra,Narendra Kurra,Meng-Qiang Zhao,Mohamed Alhabeb,Babak Anasori,Emin Caglan Kumbur,Husam N. Alshareef,Ming-Der Ger,Yury Gogotsi +11 more
TL;DR: In this paper, the fabrication of all-MXene (Ti3C2Tx) solid-state interdigital microsupercapacitors by employing a solution spray-coating method, followed by a photoresist-free direct laser cutting method was reported.