Journal ArticleDOI
Two-point and three-point methods for the investigation of electrode reaction mechanisms
TLDR
In this paper, a new method was developed for the study of first-order electrode reactions, which involves current measurements at just two selected potentials, and yields accurate values for the transfer coefficient and the exchange cd.About:
This article is published in Electrochimica Acta.The article was published on 1970-08-01. It has received 74 citations till now. The article focuses on the topics: Standard hydrogen electrode & Working electrode.read more
Citations
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Book ChapterDOI
The Polarization Resistance Technique for Measuring Corrosion Currents
TL;DR: In this article, the authors considered the classical mixed potential theory, which postulates that even without the assumption of the existence of local anodes and cathodes, one can explain corrosion reactions by assuming that cathodic and anodic partial reactions occur at the phase boundary metal/electrolyte in constant change with statistical distribution of location and time of the individual reaction.
Journal ArticleDOI
Tafel slopes and corrosion rates obtained in the pre-Tafel region of polarization curves
TL;DR: A short review of previous attempts to determine Tafel slopes and corrosion rates from data obtained in the pre-Tafel region of polarization curves is followed by a description of the approach taken in the POLFIT program as mentioned in this paper.
Journal ArticleDOI
Electrochemical measurements in flowing solutions
TL;DR: In this paper, the authors reviewed the characteristics of existing specimens and then described the development of a new design, and both the practical, including monitoring, and mechanistic significance of electrochemical measurements in flowing environments are discussed.
Journal ArticleDOI
Corrosion rates of steel in concrete
TL;DR: In this article, the authors examine DC and AC electrochemical techniques as used to determine the rate of corrosion of steel in concrete and show that film resistance and mass transport can be factors determining the rate.
Journal ArticleDOI
A review of high throughput and combinatorial electrochemistry
Tim H. Muster,Adrian Trinchi,T. Markley,D. Lau,Phil J. Martin,A. Bradbury,Avi Bendavid,Svetlana Dligatch +7 more
TL;DR: This review focuses on the utilisation of high-throughput and combinatorial methods that have incorporated, or are associated with, electrochemical methods, enabling direct quantitative analysis of properties.
References
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Journal ArticleDOI
Exchange Current Densities for Fe(II)-Fe(III) Solutions in Sulfuric Acid and Perchloric Acid
Journal ArticleDOI
Linear corrosion kinetics
TL;DR: In this paper, an analytical expression for the deviation of the linear polarization curve from the true curve is derived for the kinetic origin of extended linear polarization curves for corroding electrodes and it is shown that the ranges of validity of both anodic and cathodic linear polarities are less than 3mV at some electrodes, e.g. Fe-acid under charge-transfer control.
Journal ArticleDOI
Square wave electrolysis IV. Results and discussion
M. D. Wijnen,W. M. Smit +1 more
TL;DR: In this article, the cyclic potential-step method and cyclic current-step methods were applied to two Red/Ox systems and the results obtained by the two methods were in good agreement with each other.
Related Papers (5)
Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves
Milton Stern,A. L. Geary +1 more