Journal ArticleDOI
Vapor phase osmometric studies of alkali metal salts in acetone and tetrahydrofuran solutions
TLDR
In this article, a number of lithium and sodium salts in acetone and in tetrahydrofuran solutions in the 0·01-0·15 M concentration range were determined for a series of properties.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1972-12-01. It has received 29 citations till now. The article focuses on the topics: Tetrahydrofuran & Thiocyanate.read more
Citations
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Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms
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Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 1. Structural Data
TL;DR: Organometallic Aggregates.
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Aggregation of perchlorates in aprotic donor solvents. Part 1.—Lithium and sodium perchlorates
TL;DR: In this article, LiClO4 was investigated by IR and Raman spectroscopy and the coordination of ClO4 in the ion pairs was either monodentate or bidentate.
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1,4-Addition of Lithium Diisopropylamide to Unsaturated Esters: Role of Rate-Limiting Deaggregation, Autocatalysis, Lithium Chloride Catalysis, and Other Mixed Aggregation Effects
TL;DR: Rate and mechanistic studies have revealed that the uncatalyzed and catalyzed pathways funnel through a common monosolvated-monomer-based intermediate that causes four distinct classes of mixed aggregation effects.
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7Li, 31P, and 1H pulsed gradient spin-echo (PGSE) diffusion NMR spectroscopy and ion pairing: on the temperature dependence of the ion pairing in Li(CPh3), fluorenyllithium, and Li[N(SiMe3)2] amongst other salts.
TL;DR: 7Li, 31P, and 1H variable-temperature pulsed gradient spin-echo (PGSE) diffusion methods have been used to study ion pairing and aggregation states for a range of lithium salts such as lithium halides, lithium carbanions, and a lithium amide in THF solutions.
References
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Studies of Solvation Phenomena of Ions and Ion Pairs in Dimethoxyethane and Tetrahydrofuran
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Studies of Ions and Ion Pairs in Tetrahydrofuran Solution. Alkali Metal Salts of Tetraphenylboride
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