Journal ArticleDOI
Versatile hypervalent-iodine(III)-catalyzed oxidations with m-chloroperbenzoic acid as a cooxidant.
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This article is published in Angewandte Chemie.The article was published on 2005-09-26. It has received 282 citations till now. The article focuses on the topics: Homogeneous catalysis & Catalysis.read more
Citations
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Journal ArticleDOI
Chemistry of Polyvalent Iodine
TL;DR: The present review summarizes the data that appeared in the literature following publication of previous reviews in 1996 and 2002 and is organized according to the classes of organic polyvalent iodine compounds with emphasis on their synthetic application.
Journal ArticleDOI
Advances in Synthetic Applications of Hypervalent Iodine Compounds
TL;DR: One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.
Journal ArticleDOI
Diaryliodonium Salts: A Journey from Obscurity to Fame
TL;DR: An overview of the historical and recent advances in the synthesis and applications of diaryliodonium salts is provided.
Journal ArticleDOI
Hypervalent iodine reagents as a new entrance to organocatalysts
Toshifumi Dohi,Yasuyuki Kita +1 more
TL;DR: The historical background and the efforts made to realize the catalytic utilization of hypervalent iodine reagents are highlighted, especially with focus on iodine(iii).
Journal ArticleDOI
Comparison of Oxidative Aromatic Coupling and the Scholl Reaction
TL;DR: The authors venture the hypothesis that, depending on the electronic structure of the substrates and the nature of the "catalyst", two different mechanisms can operate, one involves the intermediacy of a radical cation and the other the formation of a sigma complex between the acid and the substrate.
References
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Journal ArticleDOI
Recent Developments in the Chemistry of Polyvalent Iodine Compounds
Journal ArticleDOI
Hypervalent iodine chemistry in synthesis: scope and new directions.
TL;DR: This contribution summarizes recent achievements and highlights key findings and developments that will influence future research and lead to novel applications of hypervalent iodine reagents in synthesis.
Book
Hypervalent iodine in organic synthesis
TL;DR: In this article, the authors present a method for hypervalent Iodine Reagents in combination with Azido Compounds and other Reagents, such as DIB and Sodium Azide.
Journal ArticleDOI
Organohypervalent iodine: development, applications, and future directions.
TL;DR: The synthetic utility of organohypervalent iodine reagents will be illustrated by their use in the alpha-Hydroxydimethylacetal formation reaction from enolizable ketones, alpha-hydroxylation,alpha-tosyloxylation and arylation ofketones, carbon-carbon bond formation, and intramolecular cyclopropanation using iodonium ylides.
Related Papers (5)
Hypervalent iodine reagents as a new entrance to organocatalysts
Toshifumi Dohi,Yasuyuki Kita +1 more