Journal ArticleDOI
Vinyl cations in solvolysis reactions
Reads0
Chats0
About:
This article is published in Accounts of Chemical Research.The article was published on 1970-07-01. It has received 83 citations till now. The article focuses on the topics: Solvolysis.read more
Citations
More filters
Journal ArticleDOI
Trifyl activation in organic synthesis
Journal ArticleDOI
Teaching an old carbocation new tricks: Intermolecular C-H insertion reactions of vinyl cations
Stasik Popov,Brian Shao,Alex L. Bagdasarian,Tyler R. Benton,Lu-Yi Zou,Lu-Yi Zou,Zhongyue Yang,K. N. Houk,Hosea M. Nelson +8 more
TL;DR: In this article, the authors report synthetic and mechanistic studies of vinyl carbocations generated through silylium-weakly coordinating anion catalysis and find that these reactive intermediates undergo mild intermolecular carbon-carbon bond-forming reactions, including carbon-hydrogen insertion into unactivated sp3 C-H bonds and reductive Friedel-Crafts reactions with arenes.
Journal ArticleDOI
The Preparation and Chemistry of Dicationically Active Polymers of Tetrahydrofuran
Samuel Smith,Allen J Hubin +1 more
TL;DR: The anhydrides of the very strong acids, CF 3 SO 3 H and FSO 3 H, polymerize tetrahydrofuran (THF) to give a living polyether having cationic activity at each chain end.
References
More filters
Journal ArticleDOI
Small-Ring Compounds. VIII. Some Nucleophilic Displacement Reactions of Cyclopropyl, Cyclobutyl, Cyclopentyl and Cyclohexyl p-Toluenesulfonates and Halides
TL;DR: In this article, the rates and products of nucleophilic displacement reactions of cyclopropyl, cyclobutyl and cyclohexyl p-toluenesulfonates and halides were studied.
Related Papers (5)
Die Solvolyse von α‐Bromstyrolen Substitution am ungesättigten trigonalen Kohlenstoffatom
C. A. Grob,G. Cseh +1 more