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X-ray photoelectron spectroscopic study of the physical adsorption of xenon and the chemisorption of oxygen on tungsten (111)

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TLDR
In this article, an ultrahigh vacuum ESCA spectrometer has been modified such that thermal desorption behavior from the W (111) crystal can be directly compared with the Xe (3 d 5 2 ) level.
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This article is published in Surface Science.The article was published on 1974-08-01. It has received 63 citations till now. The article focuses on the topics: Chemisorption & Binding energy.

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Citations
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Initial and final state effects in the ESCA spectra of cadmium and silver oxides

TL;DR: In this article, the effects of extra-atomic relaxation on chemical shifts were examined in order to elucidate the cause of the anomalous chemical shifts for Cd and Ag oxides.
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Core-level binding-energy shifts at surfaces and in solids

TL;DR: A review of core-level binding energy shifts observed in photoelectron spectroscopy can be found in this paper, where the authors focus on shifts since most of the chemical and physical insights provided by core levels are derived not from the core energies themselves but from shifts they exhibit.
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Chemisorption on metals

TL;DR: In this paper, a critical analysis of these results, especially theoretical ones, with emphasis on the relationship to simple models of chemisorption, is presented, and a discussion, in detail, of the theoretical and some experimental aspects of a number of systems is given.
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Preparation of atomically clean surfaces of selected elements: A review

TL;DR: In this article, a review of in-situ surface cleaning procedures for seventy four of the elements having vapor pressures below 1.3 × 10−7 Pa at room temperature have been reviewed and evaluated.
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Physical adsorption of xenon in open single walled carbon nanotubes: Observation of a quasi-one-dimensional confined Xe phase

TL;DR: The adsorption of Xe into carbon single walled nanotubes with both closed and open ends has been investigated using temperature programmed desorption and other surface analytical tools as mentioned in this paper.
References
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Journal ArticleDOI

Thermal desorption of gases

TL;DR: In this paper, the activation energy, rate constant and order of reaction from flash-filament desorption experiments were examined, and two heating schedules were considered: a linear variation of sample temperature with time (T = T 0+st), and a reciprocal temperature variation (1 T = 1 T 0 −αt).
Book

ESCA applied to free molecules

Kai Siegbahn
Journal ArticleDOI

Attenuation lengths of low-energy electrons in solids

TL;DR: In this article, a compilation of measured attenuation lengths of low-energy electrons in solids in the energy range (40 to 2000 eV) normally employed in X-ray photoelectron and Auger-electron spectroscopy is presented.
Journal ArticleDOI

Binding States of Hydrogen on Tungsten

TL;DR: The binding states, adsorbate densities, and desorption kinetics of hydrogen on the (110), (111), and (100) crystal planes of tungsten are examined in this paper.