Are there any reactions that use sodium chlorate?
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Sodium chlorate (NaClO3) is used as an oxidant in various reactions. It has been demonstrated to be an efficient and versatile oxidant in catalytic C–H activation reactions, such as the oxidative annulation of aryl sulfonamides with alkynes . NaClO3 has also been used in the catalytic C—H activation of N-(8-quinolyl) substituted sulfonamides, resulting in the formation of sultams . Additionally, NaClO3 has been utilized in the oxidation of tertiary amines to lactams, providing good selectivity and high yield . These reactions highlight the potential of NaClO3 as a cheap and environmentally friendly oxidant, as it eliminates the need for transition-metal catalysts and buffer salts, allowing for safe and benign reaction conditions .
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| Papers (5) | Insight |
|---|---|
10 Citations | The paper does not mention any specific reactions that use sodium chlorate. The provided paper is about the kinetics of crystal growth, dissolution, and agglomeration of sodium chlorate. |
9 Citations | The paper mentions the use of sodium chlorite in two key reactions, but it does not mention the use of sodium chlorate. |
| Yes, the paper demonstrates that sodium chlorate (NaClO3) can be used as an oxidant in the catalytic C—H activation of N-(8-quinolyl) substituted sulfonamides, which react with alkynes to give sultams in good yields. | |
20 Citations | Yes, the paper mentions that sodium chlorate is used as an oxidant in the catalytic C-H activation reaction for the oxidative annulation of aryl sulfonamides with alkynes. |
2 Citations | The paper does not mention the use of sodium chlorate. The paper is about the oxidation of tertiary amines to lactams using sodium chlorite. |
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