What is the effect of the temperature on cyclic voltammogram (CV)?
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The effect of temperature on cyclic voltammetry (CV) is significant in influencing electrochemical properties. Lowering the temperature can expand the potential window for electrochemical experiments in certain solvents like HNO3, while decreasing the temperature can hinder ionic movements in poly(o-toluidine) films, leading to a decrease in the voltammetric capacitive current associated with the redox process . Additionally, the peak current for oxidation processes decreases with temperature, and peak potentials shift with temperature variations, showcasing the impact of thermal changes on electrochemical behavior . Furthermore, the interfacial model proposed for electro-thermal coupling demonstrates a non-monotonic relationship between capacitance and bulk electrolyte density, emphasizing the intricate interplay between temperature and electrochemical performance .
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| Temperature influences cyclic voltammograms during lead electrodeposition, studied at 25-75 °C using various substrates. The temperature variation impacts the electrochemical behavior observed in the CVs. | |
29 May 2023 | Temperature affects cyclic voltammetry by influencing the integral capacitance of supercapacitors, showing an initial increase followed by a decrease due to electrical attraction and Born repulsion competition. |
| Temperature affects cyclic voltammetry by influencing capacitance in supercapacitors. The integral capacitance initially increases then decreases with rising heat bath temperature due to interplay of molecular interactions. | |
01 Jan 2014 1 Citations | Temperature affects cyclic voltammogram by expanding the potential window in aqueous HNO3, reducing peak splitting, and lowering diffusion and rate constants, leading to extended solvent windows and altered redox species behavior. |
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