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Adam C. Whalley
Researcher at University of Vermont
Publications - 34
Citations - 4147
Adam C. Whalley is an academic researcher from University of Vermont. The author has contributed to research in topics: Conductance & Density functional theory. The author has an hindex of 22, co-authored 33 publications receiving 3619 citations. Previous affiliations of Adam C. Whalley include Columbia University & Northwestern University.
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Journal ArticleDOI
Large-Pore Apertures in a Series of Metal-Organic Frameworks
Hexiang Deng,Sergio Grunder,Kyle E. Cordova,Cory Valente,Hiroyasu Furukawa,Mohamad Hmadeh,Felipe Gándara,Adam C. Whalley,Zheng Liu,Shunsuke Asahina,Hiroyoshi Kazumori,Michael O'Keeffe,Osamu Terasaki,Osamu Terasaki,J. Fraser Stoddart,J. Fraser Stoddart,Omar M. Yaghi,Omar M. Yaghi +17 more
TL;DR: A strategy to expand the pore aperture of metal-organic frameworks (MOFs) into a previously unattained size regime (>32 angstroms) is reported, as evidenced by their permanent porosity and high thermal stability (up to 300°C).
Journal ArticleDOI
Contact Chemistry and Single-Molecule Conductance : A Comparison of Phosphines, Methyl Sulfides, and Amines
Young S. Park,Adam C. Whalley,Maria Kamenetska,Michael L. Steigerwald,Mark S. Hybertsen,Colin Nuckolls,Latha Venkataraman +6 more
TL;DR: It is found that junctions formed with dimethyl phosphine terminated alkanes have the highest conductance and this allows a detailed analysis of the single-molecule junction elongation properties which correlate well with calculations based on density functional theory.
Journal ArticleDOI
Electronics and Chemistry: Varying Single-Molecule Junction Conductance Using Chemical Substituents
Latha Venkataraman,Young S. Park,Adam C. Whalley,Colin Nuckolls,Mark S. Hybertsen,Michael L. Steigerwald +5 more
TL;DR: The results reveal that the occupied states are closest to the gold Fermi energy, indicating that the tunneling transport through these molecules is analogous to hole tunneling through an insulating film.
Journal ArticleDOI
Reversible Switching in Molecular Electronic Devices
TL;DR: The change in conductance when molecules wired between the ends of individual single-walled carbon nanotubes are switched between different states of conjugation is compared.
Journal ArticleDOI
Formation and evolution of single-molecule junctions.
Maria Kamenetska,Max Koentopp,Adam C. Whalley,Young S. Park,Michael L. Steigerwald,Colin Nuckolls,Mark S. Hybertsen,Latha Venkataraman +7 more
TL;DR: Analysis of formation and evolution statistics of single-molecule junctions bonded to gold electrodes using amine, methyl sulfide, and dimethyl phosphine link groups shows sequences of atomic-scale changes in junction structure that account for the long conductance plateau lengths observed.