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Alexander J. M. Miller
Researcher at University of North Carolina at Chapel Hill
Publications - 106
Citations - 7313
Alexander J. M. Miller is an academic researcher from University of North Carolina at Chapel Hill. The author has contributed to research in topics: Catalysis & Hydride. The author has an hindex of 35, co-authored 97 publications receiving 5912 citations. Previous affiliations of Alexander J. M. Miller include California Institute of Technology & University of Chicago.
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Journal ArticleDOI
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
Gregory R. Fulmer,Alexander J. M. Miller,Nathaniel H. Sherden,Hugo E. Gottlieb,Abraham Nudelman,Brian M. Stoltz,John E. Bercaw,Karen I. Goldberg +7 more
TL;DR: Tables of 1H and 13C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents as discussed by the authors.
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E-Type Delayed Fluorescence of a Phosphine-Supported Cu2(μ-NAr2)2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs∥
Joseph Charles Deaton,Steven C. Switalski,Denis Y. Kondakov,Ralph H. Young,Thomas D. Pawlik,David J. Giesen,Seth B. Harkins,Alexander J. M. Miller,Seth F. Mickenberg,Jonas C. Peters +9 more
TL;DR: The function of the emissive dopant in OLEDs was further probed by several physical methods, including electrically detected EPR, cyclic voltammetry, and photoluminescence in the presence of applied current.
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Thermodynamic Hydricity of Transition Metal Hydrides
Eric S. Wiedner,Matthew B. Chambers,Catherine L. Pitman,R. Morris Bullock,Alexander J. M. Miller,Aaron M. Appel +5 more
TL;DR: Methods for using hydricity values to predict chemical reactivity are discussed, including organic transformations, the reduction of CO2, and the production and oxidation of hydrogen.
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Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO
Jonathan M. Smieja,Eric E. Benson,Bhupendra Kumar,Kyle A. Grice,Candace S. Seu,Alexander J. M. Miller,James M. Mayer,Clifford P. Kubiak +7 more
TL;DR: The effects of electrode surface modification on interfacial electron transfer between a semiconductor and catalyst were investigated and found to affect the observed current densities for catalysis more than threefold, indicating that the properties of the electrode surface need to be addressed when developing a homogeneous artificial photosynthetic system.
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A two-coordinate nickel imido complex that effects C-H amination
TL;DR: Computational studies showed a Ni═N bond dominated by Ni(dπ)−N(pπ) interactions, resulting in two nearly degenerate singly occupied molecular orbitals (SOMOs) that are Ni−N π* in character.