Considering metal oxide nanoparticles as important technological materials, authors provide a comprehensive review of researches on metal oxide nanoparticles, their synthetic strategies, and techniques, nanoscale physicochemical properties, defining specific industrial applications in the various fields of applied nanotechnology. This work expansively reviews the recent developments of semiconducting metal oxide gas sensors for environmental gases including CO2, O2, O3, and NH3; highly toxic gases including CO, H2S, and NO2; combustible gases such as CH4, H2, and liquefied petroleum gas; and volatile organic compounds gases. The gas sensing properties of different metal oxides nanoparticles towards specific target gases have been individually discussed. Promising metal oxide nanoparticles for sensitive and selective detection of each gas have been identified. This review also categorizes metal oxides sensors by analyte gas and also summarizes the major techniques and synthesis strategies used in nanotechnology. Additionally, strategies, sensing mechanisms and related applications of semiconducting metal oxide materials are also discussed in detail. Related applications are innumerable trace to ultratrace-level gas sensors, batteries, magnetic storage media, various types of solar cells, metal oxide nanoparticles applications in catalysis, energy conversion, and antennas (including microstrip and patch-type optically transparent antennas), rectifiers, optoelectronic, and electronics.

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Metal oxide nanoparticles and their applications in nanotechnology

https://www.econstor.eu/bitstream/10419/244006/1/1693663112.pdf

Enhanced sensing performance of ZnO nanostructures-based gas sensors: A review

Chemiresistive gas sensors with low power consumption, fast response, and reliable fabrication process for a specific target gas have been now created for many applications. They require both sensitive nanomaterials and an efficient substrate chip for heating and electrical addressing. Herein, a near room working temperature and fast response triethylamine (TEA) gas sensor has been fabricated successfully by designing gold (Au)-loaded ZnO/SnO2 core-shell nanorods. ZnO nanorods grew directly on Al2O3 flat electrodes with a cost-effective hydrothermal process. By employing pulsed laser deposition (PLD) and DC-sputtering methods, the construction of Au nanoparticle-loaded ZnO/SnO2 core/shell nanorod heterostructure is highly controllable and reproducible. In comparison with pristine ZnO, SnO2, and Au-loaded ZnO, SnO2 sensors, Au-ZnO/SnO2 nanorod sensors exhibit a remarkably high and fast response to TEA gas at working temperatures as low as 40 °C. The enhanced sensing property of the Au-ZnO/SnO2 sensor is also discussed with the semiconductor depletion layer model introduced by Au-SnO2 Schottky contact and ZnO/SnO2 N-N heterojunction.

Near Room Temperature, Fast-Response, and Highly Sensitive Triethylamine Sensor Assembled with Au-Loaded ZnO/SnO2 Core–Shell Nanorods on Flat Alumina Substrates

This work reports the synthesis and detailed investigation on ZnO–SnO 2 composite type hydrogen sensor prototype. The sensor material was structurally and morphologically characterized by X-ray diffraction technique and scanning electron microscopy, respectively. The gas sensing behaviour of the fabricated sensor prototype was investigated for varied concentration of test gases at different temperature. The cross-response of this sensor to other gases, viz. methane and carbon mono-oxide was also investigated, which showed good selectivity, excellent response and reproducibility to hydrogen at 150 °C.

ZnO–SnO2 based composite type gas sensor for selective hydrogen sensing

Recent advances in energy-saving chemiresistive gas sensors: A review

A low power MEMS gas sensor based on nanocrystalline ZnO thin films for sensing methane

Surface plasmon resonance (SPR) sensors present a challenge when high sensitivity and small FWHM (full width at half maximum) are required to be achieved simultaneously. FWHM is defined by the difference between the two extreme values of the independent variable at which the value of the dependent variable is equal to half of its maximum. A smaller value of FWHM indicates better accuracy of SPR measurements. Theoretically, many authors have claimed the possibility of simultaneously achieving high sensitivity and small FWHM, which in most of the cases has been limited by experimental validation. In this report, an experimental study on the improved surface plasmon resonance (SPR) characteristics of gold over silver bimetallic sensor chips of different film thicknesses is presented. A comparative study of antigen–antibody interaction of the bimetallic chip using a custom-made, low-cost, and portable SPR device based on an angular interrogation scheme of Kretschmann configuration is performed. Pulsed direct current (DC) magnetron-sputtered bimetallic films of gold over silver were used in the construction of the SPR chip. The FWHM and sensitivity of the bimetallic sensors were firstly characterized using standard solutions of known refractive index which were later immobilized with monoclonal anti-immunoglobulin G (IgG) in the construction of the SPR biochip. Spectroscopic measurements such as ultraviolet–visible light spectroscopy (UV–Vis) and Fourier-transform infrared spectroscopy (FTIR) were used for the confirmation of the immobilization of the antibody. The performance of the bimetallic SPR biochip was investigated by exposing the sensor to various concentrations of the target protein. The results indicated that the bimetallic sensors of silver/gold had a 3.5-fold reduced FWHM compared to pure gold-based sensors, indicating a higher detection accuracy. In addition, they exhibited a significant shift in resonance angle as high as 8.5 ± 0.2 due to antigen–antibody interaction, which was ~1.42-fold higher than observed for pure silver-based sensors.

Enhanced Biosensing Activity of Bimetallic Surface Plasmon Resonance Sensor

Thin films of metal-oxide with integrated microheater on micromachined silicon substrate have attracted great deal of interest towards the development of extremely small and highly sensitive gas sensor. Fabrication of MEMS microheater which is the key component for the development of low power gas sensor is reported here. The microheater is fabricated in a novel co planer fashion where the heating element and the inter-digitated electrode are place side by side. The fabricated device is structurally and electrically characterized by SEM and I---V measurements. Using ZnO---SnO2 composite material, hydrogen sensor was constructed on the microheater platform. A suitable package for encapsulating the fabricated device is designed and the device was successfully mounted on it. The sensing behavior of the packaged sensor is performed by exposing the sensor to hydrogen.

Biplob Mondal

Papers

ZnO–SnO2 based composite type gas sensor for selective hydrogen sensing

A low power MEMS gas sensor based on nanocrystalline ZnO thin films for sensing methane

Enhanced Biosensing Activity of Bimetallic Surface Plasmon Resonance Sensor

Fabrication and packaging of MEMS based platform for hydrogen sensor using ZnO---SnO2 composites

Quantitative recognition of flammable and toxic gases with artificial neural network using metal oxide gas sensors in embedded platform