C
C. David Garner
Researcher at University of Nottingham
Publications - 29
Citations - 950
C. David Garner is an academic researcher from University of Nottingham. The author has contributed to research in topics: Ligand & Hydrogen bond. The author has an hindex of 15, co-authored 29 publications receiving 905 citations.
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Journal ArticleDOI
Dimethylsulfoxide reductase: an enzyme capable of catalysis with either molybdenum or tungsten at the active site.
Lisa J. Stewart,Lisa J. Stewart,Susan Bailey,Brian Bennett,John M. Charnock,C. David Garner,A. S. McAlpine +6 more
TL;DR: In this paper, it has been shown that tungsten in W-DMSOR is ligated by the dithiolene group of the two pyranopterins, the oxygen atom of Ser147 plus another oxygen atom, and is located in a very similar site to that of molybdenum in Mo-dMSOR, consistent with W L(III)-edge X-ray absorption, EPR and UV/visible spectroscopic data.
Journal ArticleDOI
A phenol–imidazole pro-ligand that can exist as a phenoxyl radical, alone and when complexed to copper(II) and zinc(II)
Laurent Benisvy,Alexander J. Blake,David Collison,E. Stephen Davies,C. David Garner,Eric J. L. McInnes,Jonathan McMaster,Gavin Whittaker,Claire Wilson +8 more
TL;DR: A new N,O-bidentate, phenol-imidazole pro-ligand 2′-(4′,6′-di-tert-butylhydroxyphenyl)-4,5-diphenyl imidazoles (LH) has been designed, synthesised, and characterised as mentioned in this paper.
Journal ArticleDOI
Phenoxyl Radicals Hydrogen‐Bonded to Imidazolium: Analogues of Tyrosyl D. of Photosystem II: High‐Field EPR and DFT Studies
Laurent Benisvy,Robert Bittl,Eberhard Bothe,C. David Garner,Jonathan McMaster,Stephanie H. K. Ross,Christian Teutloff,Frank Neese +7 more
Journal ArticleDOI
Dithiolene complexes and the nature of molybdopterin
TL;DR: In this paper, the development of the coordination chemistry of dithiolene ligands is summarised, together with a consideration of the electronic structure of complexes of these ‘non-innocent’ ligands.
Journal ArticleDOI
Phenoxyl radicals: H-bonded and coordinated to Cu(II) and Zn(II)
Laurent Benisvy,Eckhard Bill,Alexander J. Blake,David Collison,E. Stephen Davies,C. David Garner,Graeme McArdle,Eric J. L. McInnes,Jonathan McMaster,Stephanie H. K. Ross,Claire Wilson +10 more
TL;DR: Electrochemical and UV/vis and EPR properties of the products indicate that each oxidation is ligand-based, and a suitable pro-ligand design allows a relatively inert phenoxyl radical to be generated, stabilised by either a hydrogen bond, as in [(R)LH] (+) (R = Bz or PhOMe), or by coordination to a metal, asIn [M(II)(( R)L)((R) L )](+)