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David E. Cliffel
Researcher at Vanderbilt University
Publications - 159
Citations - 6511
David E. Cliffel is an academic researcher from Vanderbilt University. The author has contributed to research in topics: Photosystem I & Electrode. The author has an hindex of 43, co-authored 148 publications receiving 5962 citations. Previous affiliations of David E. Cliffel include Wilmington University & United States Military Academy.
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Journal ArticleDOI
Synthesis and Catalytic Properties of Soluble Platinum Nanoparticles Protected by a Thiol Monolayer
Sven Eklund,David E. Cliffel +1 more
TL;DR: Differences in the catalytic hydrogenation rates among the various monolayer coatings for MPCs are attributed to the variations in ligand chain length, branching, charged functional groups, packing density, and core size.
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Short-Chain PEG Mixed-Monolayer Protected Gold Clusters Increase Clearance and Red Blood Cell Counts
TL;DR: The results indicate that short-chain-length PEGs, regardless of termini, increase clearance rates compared to the previous long-chain PEG studies, while carboxylated termini increase red blood cell counts at high loadings, as well as the effects of a hydroxyl versus a carboxylic acid terminal functional group on the end of the PEG thiol on both clearance and immune response.
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Enhanced photocurrents of photosystem I films on p-doped silicon.
TL;DR: Tuning the Fermi energy of silicon through doping leads to alignment of silicon bands with the redox active sites of photosystem I, which results in the highest reported photocurrent enhancement for a biohybrid electrode based on Photosystem I.
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NanoLiterBioReactor: long-term mammalian cell culture at nanofabricated scale.
Ales Prokop,Zdenka Prokop,David K. Schaffer,Eugene Kozlov,John P. Wikswo,David E. Cliffel,Franz J. Baudenbacher +6 more
TL;DR: It is concluded that an instrumented microfluidics-based NanoBioReactor (NBR) will represent a dramatic departure from the standard culture environment and opens a new paradigm of cell biology, so far largely neglected in the literature.
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Rapid assembly of photosystem I monolayers on gold electrodes.
TL;DR: It is demonstrated that a critically dense monolayer of spinach-derived PSI must be formed on an electrode surface to achieve optimal photocurrents, and a new method for preparing these dense PSI monolayers is introduced that reduces the time required for assembly by approximately 80-fold in comparison to that for adsorption from solution.