David E. Cliffel

TL;DR: First-principles calculations are reported describing a reaction between 2,4-dinitrotoluene (DNT) and atmospheric O(2) catalyzed by Fe-porphyrin at room temperature, incorporating an oxygen into the methyl group of DNT and releasing 1.9 eV per reaction.

TL;DR: This model is developed and optimize to replicate the significant electrochemical, physicochemical, and transport processes that underpin photocurrent development of a PSI multilayer film and provides strong evidence that PSI's terminal cofactors rapidly exchange electrons with diffusible mediators and stimulate photocurrent principally due to alteration of mediator concentrations at a solution-electrode interface as governed by Butler-Volmer kinetics.

TL;DR: The composite polymer-PSI assembly enhances the charge-shuttling processes from individual protein molecules within the PSI multilayer, greatly reducing charge-transfer resistances and demonstrating a much higher photocurrent than the corresponding photoelectrochemical cell built using a similar architecture.

TL;DR: Real-time multianalyte microphysiometry was used to dynamically assess multiple markers of aerobic and anaerobic respiration through simultaneous electrochemical measurement of extracellular glucose, lactate, oxygen, and acid and suggest that lactate release is not predictive of neuronal survival.

TL;DR: The impairment of ROS by HNE suggests that HNE has a greater role in foam cell formation and tissue damage than is already known and identifies PKC as a key protein for HNE suppression and eventual metabolic response.