Showing papers by "Deyu Li published in 2021"

Observation of superdiffusive phonon transport in aligned atomic chains.

Abstract: Fascinating phenomena can occur as charge and/or energy carriers are confined in one dimension1–4. One such example is the divergent thermal conductivity (κ) of one-dimensional lattices, even in the presence of anharmonic interatomic interactions—a direct consequence of the Fermi–Pasta–Ulam–Tsingou paradox proposed in 19555. This length dependence of κ, also known as superdiffusive phonon transport, presents a classical anomaly of continued interest6–9. So far the concept has remained purely theoretical, because isolated single atomic chains of sufficient length have been experimentally unattainable. Here we report on the observation of a length-dependent κ extending over 42.5 µm at room temperature for ultrathin van der Waals crystal NbSe3 nanowires. We found that κ follows a 1/3 power law with wire length, which provides experimental evidence pointing towards superdiffusive phonon transport. Contrary to the classical size effect due to phonon-boundary scattering, the observed κ shows a 25-fold enhancement as the characteristic size of the nanowires decreases from 26 to 6.8 nm while displaying a normal–superdiffusive transition. Our analysis indicates that these intriguing observations stem from the transport of one-dimensional phonons excited as a result of elastic stiffening with a fivefold enhancement of Young’s modulus. The persistent divergent trend of the observed thermal conductivity with sample length reveals a real possibility of creating novel van der Waals crystal-based thermal superconductors with κ values higher than those of any known materials. A 1/3 power law between thermal conductivity and length of a NbSe3 nanowire is observed, pointing towards a superdiffusive heat transport regime.

Reconfigurable Metasurface for Image Processing.

Abstract: Optical Fourier transform-based processing is an attractive technique due to the fast processing times and large-data rates. Furthermore, it has recently been demonstrated that certain Fourier-based processors can be realized in compact form factors using flat optics. The flat optics, however, have been demonstrated as static filters where the operator is fixed, limiting the applicability of the approach. Here, we demonstrate a reconfigurable metasurface that can be dynamically tuned to provide a range of processing modalities including bright-field imaging, low-pass and high-pass filtering, and second-order differentiation. The dynamically tunable metasurface can be directly combined with standard coherent imaging systems and operates with a numerical aperture up to 0.25 and over a 60 nm bandwidth. The ability to dynamically control light in the wave vector domain, while doing so in a compact form factor, may open new doors to applications in microscopy, machine vision, and sensing.

Resonance in Atomic-Scale Sliding Friction

Abstract: Friction represents a major energy dissipation mode, yet the atomistic mechanism of how friction converts mechanical motion into heat remains elusive. It has been suggested that excess phonons are mainly excited at the washboard frequency, the fundamental frequency at which relative motion excites the interface atoms, and the subsequent thermalization of these nonequilibrium phonons completes the energy dissipation process. Through combined atomic force microscopy measurements and atomistic modeling, here we show that the nonlinear interactions between a sliding tip and the substrate can generate excess phonons at not only the washboard frequency but also its harmonics. These nonequilibrium phonons can induce resonant vibration of the tip and lead to multiple peaks in the friction force as the tip sliding velocity ramps up. These observations disclose previously unrecognized energy dissipation channels associated with tip vibration and provide insights into engineering friction force through adjusting the resonant frequency of the tip-substrate system.

Bidirectional Modulation of Contact Thermal Resistance between Boron Nitride Nanotubes from a Polymer Interlayer.

Abstract: Enhancing the thermal conductivity of polymer composites could improve their performance in applications requiring fast heat dissipation. While significant progress has been made, a long-standing issue is the contact thermal resistance between the nanofillers, which could play a critical role in the composite thermal properties. Through systematic studies of contact thermal resistance between individual boron nitride nanotubes (BNNTs) of different diameters, with and without a poly(vinylpyrrolidone) (PVP) interlayer, we show that the contact thermal resistance between bare BNNTs is largely determined by reflection of ballistic phonons. Interestingly, it is found that a PVP interlayer can either enhance or reduce the contact thermal resistance, as a result of converting the ballistic phonon dominated transport into diffusion through the PVP layer. These results disclose a previously unrecognized physical picture of thermal transport at the contact between BNNTs, which provides insights into the design of high thermal conductivity BNNT-polymer composites.

Contact Thermal Resistance between Silver Nanowires with Poly(vinylpyrrolidone) Interlayers.

Abstract: Various nanofillers have been adopted to enhance the thermal conductivity of polymer nanocomposites. While it is widely believed that the contact thermal resistance between adjacent nanofillers can play an important role in limiting thermal conductivity enhancement of composite materials, lack of direct experimental data poses a significant challenge to perceiving the effects of these contacts. This study reports on direct measurements of thermal transport through contacts between silver nanowires (AgNWs) with a poly(vinylpyrrolidone) (PVP) interlayer. The results indicate that a PVP layer as thin as 4 nm can increase the total thermal resistance of the contact by up to an order of magnitude, when compared to bare AgNWs, even with a larger contact area. On the other hand, the thermal boundary resistance for PVP/silver interfaces could be significantly lower than that between polymer-carbon nanotubes (CNTs). Analyses based on these understandings further show why AgNWs could be more effective nanofillers than CNTs.

Non-monotonic boundary resistivity for electron transport in metal nanowires

Abstract: Boundary scattering is the most widely encountered size effect in nanoscale transport phenomena, and the scattering rate is usually regarded as a constant that is proportional to the ratio of carrier velocity to the characteristic size. Here, through combined experimental measurements and numerical modeling, we show non-monotonic variations of the boundary scattering rate for free electrons in metal nanowires as temperature escalates. This observation is attributed to the change in the electron-phonon (e-ph) scattering angle as temperature reduces, which alters the surface scattering rate. In particular, at low temperatures, electrons traveling along the wire axis have to be first relaxed by e-ph scattering before they collide with the nanowire surface. Theoretical analysis indicates a transition temperature of 0.29 times Debye temperature. A theoretical model considering the effects of the scattering angle is proposed that can fit the measured experimental data for both copper and silver nanowires over a wide temperature range.