E
Edward I. Solomon
Researcher at Stanford University
Publications - 378
Citations - 26058
Edward I. Solomon is an academic researcher from Stanford University. The author has contributed to research in topics: Active site & Copper. The author has an hindex of 88, co-authored 378 publications receiving 24414 citations. Previous affiliations of Edward I. Solomon include Princeton University & University of California, Davis.
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Journal ArticleDOI
Pulsed ENDOR study of the native and high pH perturbed forms of the blue copper site in stellacyanin
Journal ArticleDOI
Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases.
Andrew W. Schaefer,Matthew T. Kieber-Emmons,Matthew T. Kieber-Emmons,Suzanne M. Adam,Kenneth D. Karlin,Edward I. Solomon +5 more
TL;DR: It is found that the phenolic proton exhibits a secondary kinetic isotope effect, consistent with the calculations for the H-bonded O-O homolysis mechanism, supporting a model in which a peroxo intermediate serves as the active H+ acceptor, and both the H+ and e- required for O- O cleavage derive from the cross-linked Tyr residue present at the active site.
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Sulfur K-edge XAS and DFT calculations on [Fe4S4]2+ clusters: effects of H-bonding and structural distortion on covalency and spin topology.
TL;DR: A magneto-structural correlation is developed for the Fe4S4 cube that is used to identify the redox-active Fe2S2 subclusters in active sites of HiPIP and ferredoxin proteins involving these clusters.
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Spectroscopic Study of [Fe2O2(5-Et3-TPA)2]3+: Nature of the Fe2O2 Diamond Core and Its Possible Relevance to High-Valent Binuclear Non-Heme Enzyme Intermediates
TL;DR: The spectroscopic properties and electronic structure of an Fe(2)(III,IV) bis-mu-oxo complex, where 5-Et(3)-TPA = tris(5-ethyl-2-pyridylmethyl)amine, are explored to determine the molecular origins of the unique electronic and geometric features of the Fe( 2)O(2) diamond core.
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Reactivity of a Cobalt(III)-Hydroperoxo Complex in Electrophilic Reactions.
TL;DR: Reactivity studies performed with the cobalt(III)-peroxo and -hydro peroxo complexes in organic functionalizations reveal that the latter is capable of conducting oxygen atom transfer with an electrophilic character, whereas the former exhibits no oxygenatom transfer reactivity under the same reaction conditions.