Farzaneh Fadaei-Tirani

TL;DR: The solid state structure, UV-visible spec-troscopy, magnetometry, and cyclic voltammetry data, along with the DFT computations of the 2-PrPh complex unambiguously confirm the presence of Pr(IV).

TL;DR: In this article, the authors describe a selection approach that allowed the identification of a novel hexanuclear Pd cage containing two types of dipyridyl ligands, and their structure was elucidated by single-crystal X-ray diffraction.

TL;DR: Under powerful and continuous light irradiation, the dissociation constant (KMSa) of the protonated metastable state (cis-MCH) is assessed for the first time experimentally, and it is found that thermal ring-opening of SP is always rate-determining regardless of pH, whereas hydrolysis is reminiscent of what is found for Schiff bases.

TL;DR: A diuranium(v) bis-nitride complex supported by siloxide ligands displays remarkable reactivity in ambient conditions with small molecules such as CS2, CO2,CO and H2 resulting in N–C and N–H bond formation.