Filippo Monti

TL;DR: Herein, it is shown how these complexes can be prepared and discussed their unique electronic, photophysical, and photochemical properties, and the progress in the performance of iTMCs based LECs, in terms of turn-on time, stability, efficiency, and color.

TL;DR: This work provides the definitive rationalization of the stability of [Cu(NN)(PP)](+) complexes, marking the way for future developments in this field.

TL;DR: Two series of charged iridium complexes with various carbene-based ancillary ligands are reported, which possess a low-lying triplet metal-centered ((3)MC) state mainly deactivating the excited state through nonradiative processes; in contrast, no such state is present for the :C(^)C: analogues.

TL;DR: According to theoretical geometries for the lowest triplet state, the large halogen substituents contribute to sizable distortions of specific phenylpyridine ligands for ClIrPic and BrIrPic, which are likely to play a role in the emissive and nonradiative properties when coupled with the heavy-atom effect.

TL;DR: In solutions of non-coordinating solvents, (31)P NMR studies at variable temperatures and dilution titrations confirmed that the dppm-based complex undergoes a monomer-dimer dynamic equilibrium, while the dppe-containing complex occurs as the bis-cationic dinuclear species, [Cu(2)(N)(2)(dppe)(2)](2+), within a concentration range comprised between 10(-2) and 10(-4) M.