F
Frank Girgsdies
Researcher at Fritz Haber Institute of the Max Planck Society
Publications - 182
Citations - 9795
Frank Girgsdies is an academic researcher from Fritz Haber Institute of the Max Planck Society. The author has contributed to research in topics: Catalysis & Crystal structure. The author has an hindex of 47, co-authored 178 publications receiving 8084 citations. Previous affiliations of Frank Girgsdies include Technical University of Berlin & Max Planck Society.
Papers
More filters
Journal Article
Electrochemical Surface Oxidation of Copper Studied by in Situ Grazing Incidence X-ray Diffraction
Michael Scherzer,Frank Girgsdies,Eugen Stotz,Marc Georg Willinger,Elias Frei,Robert Schlögl,Ullrich Pietsch,Thomas Lunkenbein +7 more
TL;DR: In this paper, an in situ laboratory GIXRD setup for electrochemical experiments is presented, which is capable of directly correlating changes of the crystalline surface structure to the electrochemical conditions.
Journal ArticleDOI
Oscillatory behavior in the CO-oxidation over bulk ruthenium dioxide - the effect of the CO/O2 ratio
TL;DR: In this article, the evolution of the bulk state of the catalyst was followed by in-situ XRD during reaction, while the surface morphology and chemical state before and after reaction were investigated.
Journal ArticleDOI
Synthesis and x-ray crystal structure of chiral dimethylgallium alkoxides containing diastereoisomerically pure n,n-dimethylamino alcohols
TL;DR: The reaction of trimethylgallium, GaMe3, with optically active amino alcohols was studied in this article, showing that the absolute configurations of the asymmetric centers in the 0,Nchelating bidental ligands are retained upon formation of the corresponding coordinatively saturated complexes.
Journal ArticleDOI
Tetrahedral Coordination in the First Structurally Characterized Dichlorooxovanadium(V) Alkoxide
TL;DR: In this paper, a tetrahedral coordination around the vanadium atom in the monomeric compound was found. But the structure analysis revealed an unexpected tetrahedrische coordination around vanadium.
Journal ArticleDOI
Intramolekular schwefelstabilisierte Aluminium‐ und Galliumalkyle
Abstract: Die intramolekular schwefelstabilisierten Organoaluminium- und Organogalliumverbindungen Me2Al(CH2)3SEt (1), Me2Ga(CH2)3SEt (2), MeClAl(CH2)3SEt (3), MeClGa(CH2)3SEt (4), Cl2Al(CH2)3SEt (5) und Cl2Ga(CH2)3SEt (6) werden aus Me2MCl, MeMCl2 bzw. MCl3 (M = Al, Ga) und ClMg(CH2)3SEt erhalten. Bei der Umsetzung von 5 bzw. 6 mit BrMg(CH2)5MgBr entstehen (CH2)5Al(CH2)3SEt (7) und (CH2)5Ga(CH2)3SEt (8). AlCl3 bzw. GaCl3 reagieren mit zwei bzw. drei Aquivalenten ClMg(CH2)3SEt unter Bildung von ClAl[(CH2)3SEt]2 (9) und ClGa[(CH2)3SEt]2 (10) bzw. Al[(CH2)3SEt]3 (11) und Ga[(CH2)3SEt]3 (12). Diese Verbindungen wurden durch Elementaranalysen, Massenspektren, 1H-, 13C- und 27Al-NMR-Untersuchungen sowie 6 durch Einkristall-Rontgenstrukturanalyse charakterisiert.
Intramolecularly Sulfur stabilized Aluminum and Gallium Alkyl Derivatives
The intramolecularly sulfur stabilized organoaluminum and organogallium compounds Me2Al(CH2)3SEt (1), Me2Ga(CH2)3SEt (2), MeClAl(CH2)3SEt (3), MeClGa(CH2)3SEt (4), Cl2Al(CH2)3SEt (5), and Cl2Ga(CH2)3SEt (6) are synthesized from Me2MCl, MeMCl2, and MCl3 (M = Al, Ga), respectively, and ClMg(CH2)3SEt. The reaction of 5 and of 6 with BrMg(CH2)5MgBr yields (CH2)5Al(CH2)3SEt (7) and (CH2)5Ga(CH2)3SEt (8), respectively. AlCl3 and GaCl3 react with two as well as three equivalents of ClMg(CH2)3SEt forming ClAl[(CH2)3SEt]2 (9) and ClGa[(CH2)3SEt]2 (10) as well as Al[(CH2)3SEt]3 (11) and Ga[(CH2)3SEt]3 (12), respectively. The compounds were characterized by elemental analyses, mass spectroscopy, 1H, 13C, and 27Al NMR investigations as well as 6 by single crystal X-ray structure analysis.