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Showing papers by "Franz Kreupl published in 2004"


Journal ArticleDOI
TL;DR: In this article, a planar field effect transistors (FET) consisting of a large number of parallel single-walled carbon nanotubes (SWCNT) have been fabricated that allow very high on-currents of the order of several milliamperes and on/off ratios exceeding 500.
Abstract: Planar field effect transistors (FET) consisting of a large number of parallel single-walled carbon nanotubes (SWCNT) have been fabricated that allow very high on-currents of the order of several milliamperes and on/off ratios exceeding 500. With these devices it is demonstrated, for the first time, that SWCNTs can be used as transistors to control macroscopic devices, e.g., light emitting diodes and electromotors. Those transistors were fabricated by a very simple process that is based on the catalytic chemical vapor deposition (CCVD) growth of SWCNTs at low temperatures, a single lithographic step to define the source and drain contacts, and a bias pulse to eliminate the metallic SWCNTs.

175 citations


Journal ArticleDOI
TL;DR: In this article, a phenomenological growth model for CVD synthesis of single-walled carbon nanotubes (SWCNTs) is proposed which is based on the interactions between the catalyst and its support.
Abstract: A comparison of different catalysts (Ni, Co, Fe/Mo) has been performed in order to minimize the growth temperature for single-walled carbon nanotubes (SWCNTs). Dense SWCNT networks have been synthesized by thermal chemical vapor deposition (CVD) at temperatures as low as 600 °C using Ni catalyst layers of approximately 0.2 nm thickness. The dependence of the SWCNT growth on the most important parameters will be discussed exemplarily on the Ni catalyst system. On the basis of experimental observations, a phenomenological growth model for CVD synthesis of SWCNTs is proposed which is based on the interactions between the catalyst and its support. Further, it is suggested that only surface diffusion of hydrocarbons on the catalyst support or along the CNTs can explain the fast growth rates of SWCNTs during CVD synthesis.

172 citations


Book ChapterDOI
TL;DR: In this article, a simulation of an ideal carbon nanotube field effect transistors (CNTFET) is presented and compared with the requirements of the ITRS roadmap.
Abstract: The extraordinary characteristics of carbon nanotubes make them a promising candidate for applications in microelectronics. Catalyst-mediated chemical vapor deposition growth is very well suited for selective in-situ growth of nanotubes compatible with the requirements of microelectronics technology. This deposition method can be exploited for carbon nanotube vias. Semiconducting single-walled tubes can be successfully operated as carbon nanotube field effect transistors (CNTFET). A simulation of an ideal CNTFET is presented and compared with the requirements of the ITRS roadmap. Finally, we compare an upgraded CNTFET with the most advanced silicon metal oxide semiconductor field effect transistors and discuss integration issues.

130 citations


Journal ArticleDOI
TL;DR: Carbon nanotube field-effect transistors with sub-20 nm long channels and on/off current ratios of >10(6) are demonstrated and display on-currents in excess of 15 microA for drain-source biases of only 0.4 V.
Abstract: Carbon nanotube field-effect transistors with sub 20 nm long channels and on/off current ratios of > 1000000 are demonstrated. Individual single-walled carbon nanotubes with diameters ranging from 0.7 nm to 1.1 nm grown from structured catalytic islands using chemical vapor deposition at 700 degree Celsius form the channels. Electron beam lithography and a combination of HSQ, calix[6]arene and PMMA e-beam resists were used to structure the short channels and source and drain regions. The nanotube transistors display on-currents in excess of 15 microA for drain-source biases of only 0.4 Volt.

118 citations


Posted Content
TL;DR: In this article, the status of the application of carbon nanotubes (CNTs) for future interconnects and present results concerning possible integration schemes are reviewed and discussed.
Abstract: We briefly review the status of the application of carbon nanotubes (CNTs) for future interconnects and present results concerning possible integration schemes. Growth of single nanotubes at lithographically defined locations (vias) has been achieved which is a prerequisite for the use of CNTs as future interconnects. For the 20 nm node, a current density of 5 10^8 A/cm^2 and a resistance of 7.8 kOhm could be achieved for a single multi-walled CNT vertical interconnect.

82 citations


Journal ArticleDOI
TL;DR: In this paper, the electronic breakdown and bias dependence of the conductance have been investigated for a large number of catalytic chemical vapor deposition grown single-walled carbon nanotubes (SWCNTs) with very small diameters.
Abstract: The electronic breakdown and the bias dependence of the conductance have been investigated for a large number of catalytic chemical vapor deposition grown single-walled carbon nanotubes (SWCNTs) with very small diameters. The convenient fabrication of thousands of properly contacted SWCNTs was possible by growth on electrode structures and subsequent electroless palladium deposition. Almost all of the measured SWCNTs showed at least weak gate dependence at room temperature. Large differences in the conductance and breakdown behavior have been found for “normal” semiconducting SWCNTs and small band-gap semiconducting SWCNTs.

75 citations


Patent
29 Jul 2004
TL;DR: In this article, the arrangement of nanowires with PN junctions between bit lines and word lines is arranged as a ROM memory cell array, where the connections between word and bit lines may also exist as transistors which turn on or turn off only when a gate voltage is applied.
Abstract: Arrangement of nanowires with PN junctions between bit lines and word lines are arranged as a ROM memory cell array. A number of the nanowires have dielectric regions and are present only as a dummy. The connections between word and bit lines may also exist as transistors which turn on or turn off only when a gate voltage is applied. A number of these transistors are constructed in complementary fashion and/or have insulating regions built in and serve as a dummy.

33 citations


Journal ArticleDOI
TL;DR: In this article, the reaction of multi-walled carbon nanotubes (MWCNT) with xenon difluoride has been studied and compared with the results from experiments with elemental fluorine.

32 citations


Patent
29 Sep 2004
TL;DR: In this paper, an electrically conductive substrate is provided, a trench structure or cup structure with side walls and a base is formed in or on the substrate, a first insulation layer is deposited at the side walls, a capacitor material is deposited on the base, a nanostructure is grown starting from and electrically connected to the catalyst material, a second insulation layer was added on the nanostructures and on the bases, and finally an electrical conductive layer was deposited as a counterelectrode on the insulation layer.
Abstract: A method for producing memory cells, in which an electrically conductive substrate is provided, a trench structure or cup structure with side walls and a base is formed in or on the substrate, a first insulation layer is deposited at the side walls, a capacitor material is deposited on the base, a nanostructure is grown starting from and electrically connected to the catalyst material deposited on the base, a second insulation layer is deposited on the nanostructure and on the base, and finally an electrically conductive layer is deposited as a counterelectrode on the first insulation layer and second insulation layer.

31 citations


Patent
03 Nov 2004
TL;DR: In this paper, the process for contact-connection of carbon nanotubes as part of their integration in an electric circuit is described, where the nanotube, after they have been applied to metallic interconnects of the electric circuit, are connected to the interconnect at contact locations by electroless metallization.
Abstract: Process for contact-connection of carbon nanotubes as part of their integration in an electric circuit, wherein the nanotubes, after they have been applied to metallic interconnects of the electric circuit, are connected to the interconnects at contact locations by electroless metallization.

10 citations


Patent
23 Dec 2004
TL;DR: In this article, a method for depositing a conductive carbon material (17) on a semiconductor (14) for forming a Schottky contact (16) was proposed.
Abstract: The invention relates to a method for depositing a conductive carbon material (17) on a semiconductor (14) for forming a Schottky contact (16). The inventive method comprises the following steps: introducing a semiconductor (14) into a process chamber (10); heating the interior (10') of a process chamber (10) to a defined temperature; evacuating the process chamber (10) to a first defined pressure or below; heating the interior (10') of a process chamber (10) to a second defined temperature; introducing a gas (12) which comprises at least carbon, until a second defined pressure is achieved which is higher than the first defined pressure; and depositing the conductive carbon material (17) on the semiconductor (14) from the gas (12) which comprises at least carbon, whereby the deposited carbon material (17) forms the Schottky contact (16) on the semiconductor (14).

Posted Content
TL;DR: Carbon nanotubes have emerged as a possible new material for electronic applications as discussed by the authors, and they show promising characteristics for transistors as well as for interconnects and discuss the challenges facing their integration.
Abstract: Carbon nanotubes have emerged as a possible new material for electronic applications. They show promising characteristics for transistors as well as for interconnects. Here we review their basic properties and focus on the status of nanotubes with respect to their application as interconnects and discuss the challenges facing their integration.

Patent
23 Dec 2004
TL;DR: The vorliegende Erfindung stellt ein Verfahren zur Abscheidung eines leitfahigen Kohlenstoffmaterials (17) auf einem Halbleiter (14) zur Ausbildung eine Schottky-Kontaktes (16) mit den Schritten bereit: Einbringen des Halbleiters (14), in die Prozesskammer (10); Erhitzen des Innenraums (10') einer Proz
Abstract: Die vorliegende Erfindung stellt ein Verfahren zur Abscheidung eines leitfahigen Kohlenstoffmaterials (17) auf einem Halbleiter (14) zur Ausbildung eines Schottky-Kontaktes (16) mit den Schritten bereit: Einbringen des Halbleiters (14) in die Prozesskammer (10); Erhitzen des Innenraums (10') einer Prozesskammer (10) auf eine vorbestimmte Temperatur; Evakuieren der Prozesskammer (10) auf einen ersten vorbestimmten Druck oder darunter; Erhitzen des Innenraums (10') einer Prozesskammer (10) auf eine zweite vorbestimmte Temperatur; Einleiten eines Gases (12), welches zumindest Kohlenstoff aufweist, bis ein zweiter vorbestimmter Druck erreicht ist, welcher hoher als der erste vorbestimmte Druck ist; und Abscheiden des leitfahigen Kohlenstoffmaterials (17) auf dem Halbleiters (14) aus dem Gas (12), welches zumindest Kohlenstoff aufweist, wobei das abgeschiedene Kohlenstoffmaterial (17) auf dem Halbleiter (14) den Schottky-Kontakt (16) ausbildet.

Proceedings ArticleDOI
11 Nov 2004
TL;DR: In this article, the authors present a method to create vertical electrical interconnects made of carbon nanotubes (CNTs) by using CVD growth of the CNTs and the structured deposition of metallic top contacts.
Abstract: The unique properties of carbon nanotubes (CNTs) make them promising candidates for electrical conductors in microelectronic devices. The parallel integration of CNTs into processes that are compatible with the requirements of the microelectronic industry will be important for their future application in chip devices. We present lithography‐based processes to create vertical electrical interconnects made of CNTs. The approach involves catalyst and dielectric (insulator) deposition, lithography, standard etch processes, CVD growth of the CNTs, and the structured deposition of metallic top contacts. This paper will discuss the electrical properties of these CNT vertical interconnects and compare them with the requirements of the ITRS roadmap.

Patent
11 Oct 2004
TL;DR: In this paper, a microelectronic semiconductor element comprises at least one electrode comprising a carbon-containing layer and an independent claim is also included for a production process for the above.
Abstract: A microelectronic semiconductor element comprises at least one electrode comprising a carbon-containing layer. Preferably the element is a FET having a gate electrode and a source/drain electrode comprising the carbon-containing layer. An independent claim is also included for a production process for the above.

Patent
14 Dec 2004
TL;DR: In this paper, a bridge field effect transistor (BFAET) storage cell is described, consisting of a first and second source/ drain areas and a channel area arranged there between which are formed in a semiconductor bridge.
Abstract: The invention relates to a bridge field-effect transistor storage cell comprising a first and second source/ drain areas and a channel area arranged therebetween which are formed in a semiconductor bridge. The inventive storage cell also comprises a charge-coupled layer which is disposed at least partially on the semiconductor bridge and a metal conductive gate area on at least one part of said charge-coupled layer which is arranged in such a way that electric charge carriers are selectively introducible or removable by applying a predetermined electric voltage to the bridge field-effect transistor storage cell.

Patent
28 Jun 2004
TL;DR: Achlioptas et al. as mentioned in this paper weist zumindest eine Kohlenstoff-Leiterstrukturauf, welche mittels einer im wesentlichen aus Kohlen stoff bestehenden Schichtausgebildet ist, and welche einen spezifischen Widerstand von weniger ≥ 1 mΩcm
Abstract: Ein elektrischer Schaltkreis weist zumindest eine Kohlenstoff-Leiterstruktur auf, welche mittels einer im wesentlichen aus Kohlenstoff bestehenden Schicht ausgebildet ist, welche einen spezifischen Widerstand von weniger als 1 mΩcm aufweist

Patent
09 Feb 2004
TL;DR: In this article, an integrated electronic component, comprising a substrate (1), at least one metal multilayer system, which is placed on the substrate at least in areas, and comprising a nonconducting layer (50), was described.
Abstract: The invention relates to an integrated electronic component, comprising a substrate (1), at least one metal multilayer system, which is placed on the substrate at least in areas, and comprising a nonconducting layer (50), which is placed on the metal multilayer system and which has at least one contact hole, inside of which at least one nanotube is grown at the bottom of the contact hole on the metal multilayer system. The metal multilayer system is constructed from a metal layer (20) with a high melting point, a metal separation layer (30), and from a catalyst layer (40). The invention also relates to a method for specifically producing nanotubes in vertical structures, and to the use of a metal multilayer system for specifically producing nanotubes in vertical structures.

Posted Content
TL;DR: In this paper, a vertical nanotube transistor concept is proposed, which outperforms the ITRS requirements for the year 2016 in terms of transconductance, on-resistance and drive current of silicon devices.
Abstract: Carbon nanotubes with their outstanding electrical and mechanical properties are suggested as interconnect material of the future and as switching devices, which could outperform silicon devices. In this paper we will introduce nanotubes, specify the applications, where nanotubes can contribute to the advancement of Moore's law and show our progress of nanotube process integration in a microelectronic compatible way. The growth of single individual nanotubes at lithographically defined locations on whole wafers as a key requirement for the successful implementation of nanotubes is shown. In terms of nanotube transistors we propose a vertical nanotube transistor concept which outperforms the ITRS requirements for the year 2016. The performance is mainly limited by contact resistances, but by comparison with silicon devices we show that fabricated nanotube transistors already today exceed the values for transconductance, on-resistance and drive current of silicon devices.

Patent
11 Oct 2004
TL;DR: In this paper, ein elektrischer Schaltkreis weist zumindest eine Nanostruktur und eine Kohlenstoff-Leiterbahn auf, wobei die Nanostruckur und die Kohlen-stoff bestehenden Schicht im direkten Kontakt stehen.
Abstract: Ein elektrischer Schaltkreis weist zumindest eine Nanostruktur und eine Kohlenstoff-Leiterbahn auf, welche Kohlenstoff-Leiterbahn mittels einer im wesentlichen aus Kohlenstoff bestehenden Schicht ausgebildet ist, wobei die Nanostruktur und die Kohlenstoff-Leiterbahn im direkten Kontakt stehen.

Proceedings ArticleDOI
11 Nov 2004
TL;DR: A comparison of carbon nanotube field effect transistors with silicon MOSFETs shows that CNT devices outperform state-of-the-art silicon transistors as mentioned in this paper.
Abstract: Carbon nanotubes (CNTs) have a large variety of properties that make them attractive for applications in microelectronics. A comparison of carbon nanotube field‐effect transistors with silicon MOSFETs shows that CNT devices outperform state‐of‐the‐art silicon transistors. A silicon technology review gives the benchmark for an assessment of the current CNT technology and identifies the growth and placement procedures that are not yet sufficient for industrial applications. Finally, the vertical CNT transistor concept is introduced which deals with the technological problems and opens a new route for 3D integration.

Patent
11 Mar 2004
TL;DR: In this article, a process for producing a carbon layer with a specific resistance less than 1mOhmcm and a hardness of 2-9Gpa, comprises precipitating the carbon layer.
Abstract: A process for producing a carbon layer with a specific resistance less than 1mOhmcm and a hardness of 2-9Gpa, comprises precipitating the carbon layer. The substrate is in a hydrogen atmosphere with a pressure of 1-4 hectopascals and a temperature of 600-1000o>C. A gas containing carbon is added to form the carbon layer.

Patent
24 Jun 2004
TL;DR: In this article, the authors defined blanks as blanks, being interrupted by dielectric material, e.g., silica or silicon nitride, including silicon nanowires.
Abstract: of EP1505646Silicon nanowires (3) included, are blanks, being interrupted by dielectric (12), e.g. silica or silicon nitride.

Patent
09 Sep 2004
TL;DR: In this article, the authors proposed a storage device for storing electric charge, which consisted of a substrate (101), at least one storage cell (107) disposed on said substrate and comprising a first electrode element (102), an insulating layer (103) and a second electrode element(104), thereby presenting a capacitive element.
Abstract: The invention relates to a storage device (100) for storing electric charge. Said storage device comprises a substrate (101), at least one storage cell (107) disposed on said substrate (101) and comprising a first electrode element (102), an insulating layer (103) and a second electrode element (104), thereby presenting a capacitive element. The first electrode element (102) that is electrically connected to the substrate (101) is provided in the form of a nanotube (NT) that has a high aspect ratio.

Proceedings ArticleDOI
11 Nov 2004
TL;DR: In this article, a planar growth of single-walled carbon nanotubes (SWCNTs) by catalytic chemical vapor deposition (CVD) at low temperatures is reported.
Abstract: New results on the planar growth of single‐walled carbon nanotubes (SWCNTs) by catalytic chemical vapor deposition (CVD) at low temperatures will be reported. Optimizing catalyst, catalyst support, and growth parameters yields SWCNTs at temperatures as low as 600 °C. Growth at such low temperatures largely affects the diameter distribution since coalescence of the catalyst is suppressed. A phenomenological growth model will be suggested for CVD growth at low temperatures. The model takes into account surface diffusion and is an alternative to the bulk diffusion based vapor‐liquid‐solid (VLS) model. Furthermore, carbon nanotubes field effect transistors based on substrate grown SWCNTs will be presented. In these devices good contact resistances could be achieved by electroless metal deposition or metal evaporation of the contacts.

01 Jan 2004
TL;DR: In this article, a variety of carbon nanotube based electronic devices, such as interconnects, transistors, and power transformer, are presented, and some of the integration issues are discussed.
Abstract: Carbon Nanotubes seem to be one of the most promising candidates for nanoelectronic devices beyond presumable scaling limits of silicon and compound semiconductors and independent from lithographic limitations. Discovered only about a decade ago, there has been a tremendous advance in the field of carbon nanotubes. Their exciting properties, especially with respect to electronic applications, and their fabrication methods will be discussed. A variety of Carbon Nanotube based electronic devices, such as interconnects, transistors, and power transistors, will be presented. However, large-scale integration of carbon nanotubes seems to be a huge challenge. Some of the integration issues will be critically addressed and carbon nanotubes will be compared with some other nanoscale approaches.

Patent
11 Nov 2004
TL;DR: In this paper, an integriertes elektronisches Bauelement, umfassend ein Substrat, mindestens ein Metall-Mehrschichtsystem, das mindesten bereichsweise auf dem Substrats angeordnet ist, and eine, nicht-leitende Schicht, die mindestins ein Kontaktloch aufweist, worin eine Nanorohre am Boden des Kontachtlochs an dem Metall
Abstract: Die vorliegende Erfindung betrifft ein integriertes elektronisches Bauelement, umfassend ein Substrat, mindestens ein Metall-Mehrschichtsystem, das mindestens bereichsweise auf dem Substrat angeordnet ist, und eine auf dem Metall-Mehrschichtsystem angeordnete, nicht-leitende Schicht, die mindestens ein Kontaktloch aufweist, worin mindestens eine Nanorohre am Boden des Kontaktlochs an dem Metall-Mehrschichtsystem aufgewachsen ist, wobei das Metall-Mehrschichtsystem aus einer hochschmelzenden Metallschicht, einer Metalltrennschicht und einer Katalysatorschicht aufgebaut ist. Ferner betrifft die vorliegende Erfindung ein Verfahren zur gezielten Erzeugung von Nanorohren in vertikalen Strukturen sowie die Verwendung eines Metall-Mehrschichtsystems zur gezielten Herstellung von Nanorohren in vertikalen Strukturen.

Patent
23 Dec 2004
TL;DR: Invention concerne un procede servant a deposer un materiau de carbone conducteur (17) sur un semi-conducteur (14) afin de creer un contact Schottky (16) as mentioned in this paper.
Abstract: L'invention concerne un procede servant a deposer un materiau de carbone conducteur (17) sur un semi-conducteur (14) afin de creer un contact Schottky (16). Ce procede consiste a: introduire un semi-conducteur (14) dans une chambre de traitement (10), rechauffer l'interieur (10') de la chambre de traitement (10) a une temperature determinee, faire le vide dans la chambre de traitement (10) jusqu'a un niveau egal ou inferieur a une premiere pression determinee, rechauffer l'interieur (10') de la chambre de traitement (10) a un deuxieme niveau egal a une temperature determinee, introduire un gaz (12) contenant au moins du carbone, jusqu'a l'obtention d'une deuxieme pression determinee superieure a la premiere pression determinee et deposer le materiau de carbone conducteur (17) sur le semi-conducteur (14) a partir dudit gaz (12), le materiau depose (17) constituant le contact Schottky (16) sur le semi-conducteur (14).

Patent
11 Oct 2004
TL;DR: In this article, an electrical circuit includes at least one nanostructure, and a carbon conductor, which carbon-conductor track is formed by a substantially consisting of carbon layer, wherein the nanostructures and the carbon conductor track are in direct contact, wobei die Nanostruktur and die Kohlenstoff-Leiterbahn im direkten Kontakt stehen.
Abstract: Ein elektrischer Schaltkreis weist zumindest eine Nanostruktur und eine Kohlenstoff-Leiterbahn auf, welche Kohlenstoff-Leiterbahn mittels einer im wesentlichen aus Kohlenstoff bestehenden Schicht ausgebildet ist, wobei die Nanostruktur und die Kohlenstoff-Leiterbahn im direkten Kontakt stehen. An electrical circuit includes at least one nanostructure, and a carbon conductor, which carbon-conductor track is formed by a substantially consisting of carbon layer, wherein the nanostructure and the carbon-conductor track are in direct contact.

Patent
09 Feb 2004
TL;DR: In this paper, an integriertes elektronisches Bauelement, umfassend ein Substrat (10), mindestens ein Metall-Mehrschichtsystem (20), einer Metalltrennschicht (30) und einer Katalysatorschicht(40) aufgebaut ist.
Abstract: Die vorliegende Erfindung betrifft ein integriertes elektronisches Bauelement, umfassend ein Substrat (10), mindestens ein Metall-Mehrschichtsystem, das mindestens bereichsweise auf dem Substrat angeordnet ist, und eine auf dem MetallMehrschichtsystem angeordnete, nicht-leitende Schicht (50), die mindestens ein Kontaktloch aufweist, worin mindestens eine Nanorohre am Boden des Kontaktlochs an dem Metall-Mehrschichtsystem aufgewachsen ist, wobei das Metall-Mehrschichtsystem aus einer hochschmelzenden Metallschicht (20), einer Metalltrennschicht (30) und einer Katalysatorschicht (40) aufgebaut ist. Ferner betrifft die vorliegende Erfindung ein Verfahren zur gezielten Erzeugung von Nanorohren in vertikalen Strukturen sowie die Verwendung eines Metall-Mehrschichtsystems zur gezielten Herstellung von Nanorohren in vertikalen Strukturen.