Fujio Izumi

TL;DR: How bonds are broken and formed in these significant molecular rearrangements are demonstrated and how the initial arrangement plays a crucial role in the formation of the new networks after the CAC transformations are demonstrated.

TL;DR: Temperature-driven Li displacements indicate that the conduction pathways in the garnet framework are restricted to diffusion through the tetrahedral sites of the interstitial space.

TL;DR: In this paper, the intercalation of pyridine has been examined for four types of layered protonic titanates such as H2Ti3O7, HTi4O9·1.2H2O, H2 Ti5O11·3 H2O and HxTi2-x/4□x/ 4O4·H 2O (x ∼ 0.7, □: vacancy).

TL;DR: A porous coordination network was cleanly obtained after a crystalline-to-amorphous- to-crystalline phase transition, and the crystal structure was unambiguously solved by ab initio powder X-ray diffraction.

TL;DR: It is demonstrated that the relative stability between structure-I and structure-II hydrates is primarily determined by kinetically controlled cage filling and associated binding energies, which is fundamentally important to understanding clathrate formation, structure stabilization and the role the dipole moment/molecular polarizability plays in these processes.