F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
Papers
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Ruthenium-Catalyzed Ortho C-H Arylation of Aromatic Nitriles with Arylboronates and Observation of Partial Para Arylation.
TL;DR: Ruthenium-catalyzed C-H arylation of aromatic nitriles with arylboronates is described, and the cyano group was also found to function as a directing group for cleavage of C-O bonds in aRYl ethers.
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RuH2(CO)(PPh3)3-catalyzed arylation of aromatic esters using arylboronates via C–H bond cleavages
TL;DR: The RuH 2 (CO)(PPh 3 ) 3 -catalyzed C-H functionalization of aromatic esters with 5,5-dimethyl-2-aryl-[1,3,2]dioxaborinanes (arylboronates) gave the ortho arylation products as mentioned in this paper.
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Efficient Catalytic Addition of Aromatic Carbon‐Hydrogen Bonds to Olefins.
Shinji Murai,Fumitoshi Kakiuchi,S. Sekine,Yasuo Tanaka,Asayuki Kamatani,Motohiro Sonoda,Naoto Chatani +6 more
TL;DR: The selective cleavage of carbon-hydrogen bonds in organic compounds is a critical step in many organic syntheses, and is particularly important in the conversion of hydrocarbons to useful organic compounds as mentioned in this paper.
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Selective C−H Functionalizations by Electrochemical Reactions with Palladium Catalysts
Fumitoshi Kakiuchi,Takuya Kochi +1 more
TL;DR: In this article, a review of transition-metal-catalyzed efficient and selective C−H functionalization by electrochemical reactions is presented, where the authors briefly survey the literature.
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Synthesis of [Ru(CO)2(PPh3)(SP)] and [Ru(CO)(PPh3)2(SP)] and their catalytic activities for the hydroamination of phenylacetylene
TL;DR: In this article, the spectral and X-ray data of these complexes revealed that the coordination geometries around the ruthenium center corresponded to a distorted trigonal bipyramid with the olefin occupying the equatorial position.