F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
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Journal ArticleDOI
Ruthenium-Catalyzed Addition of Carbon–Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring
TL;DR: In this article, the effect of various substituents at the aromatic ring is examined and the ruthenium-catalyzed reaction of carbon-hydrogen bonds in aromatic ketones with olefins is obtained.
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Cleavage of C−N Bonds in Aniline Derivatives on a Ruthenium Center and Its Relevance to Catalytic C−C Bond Formation
TL;DR: The present results suggest that ruthenium-catalyzed C-C bond formation from o-acylaniline and organoboronate proceeds via direct C-N bond cleavage on the r Ruthenium center.
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A New Chelation-Assistance Mode for a Ruthenium-Catalyzed Silylation at the C-H Bond in Aromatic Ring with Hydrosilanes
Fumitoshi Kakiuchi,Kimitaka Igi,Mitsutaka Matsumoto,Tomoo Hayamizu,Naoto Chatani,Shinji Murai +5 more
TL;DR: In this paper, the authors showed that the reactive substrates with π-conjugation between the hetero atom in the directing group and the carbon atom possessing the C-H bond to be cleaved were used.
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Catalytic Addition of Olefinic C–H Bonds to Olefins
TL;DR: In this article, the addition of C-H bonds in α,β-enones to olefins was attained by Ru(H)2(CO)(PPh3)3 catalyst.
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Room-temperature regioselective C-H/olefin coupling of aromatic ketones using an activated ruthenium catalyst with a carbonyl ligand and structural elucidation of key intermediates.
TL;DR: NMR studies of the C-H/olefin coupling at room temperature suggested that an ortho-ruthenated complex, P,P'-cis-C,H- cis-Ru(2'-(6'-MeC(6)H(4)C(O)Me))(H)(CO)(PPh(3))(2), participated in the reaction as a key intermediate.