F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
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Rhodium‐Catalyzed anti‐Markovnikov Intermolecular Hydroalkoxylation of Terminal Acetylenes.
TL;DR: In this paper, the process was successfully achieved using QOR to give enol ethers with high (Z)-selectivity, which was achieved by using a QOR-based algorithm.
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Regioselective C—H Bond Cleavage/Alkyne Insertion under Ruthenium Catalysis.
TL;DR: The ruthenium-catalyzed coupling reactions of benzamides with alkynes in the presence of acetic acid as a promoter smoothly proceeded regio-and stereoselectively through a directed C-H bond cleavage to produce the corresponding ortho-alkenylated products as discussed by the authors.
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New Synthetic Protocol in Organic Synthesis
TL;DR: In this paper, a chelation-assisted C-H bond cleavage protocol is proposed for catalytic addition of carbon-hydrogen bonds to olefins and acetylenes.
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Ruthenium-catalyzed alkylation of aromatic ketones with olefins: 8-[2-(triethoxysilyl)ethyl]-1-tetralone: [(1(2h)-naphthalenone, 3,4-dihydro-8-[2-(triethoxysilyl)ethyl]-)]
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Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Aliphatic and Aromatic Terminal Alkynes with Aliphatic Primary Amines.
TL;DR: In this article, an 8-quinolinolato rhodium catalyst was used to form aldimines and enamines in high yields with high functional group tolerance including hydroxy, bromo, cyano, and thioester groups.