F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
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Ru3(CO)12-catalyzed silylation of benzylic C-H bonds in arylpyridines and arylpyrazoles with hydrosilanes via C-H bond cleavage.
TL;DR: Ruthenium-catalyzed silylation of sp3 C-H bonds at a benzylic position with hydrosilanes gave benzylsilanes and Ru3(CO)12 complex showed high catalytic activity.
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Ru3(CO)12-Catalyzed Decarbonylative Cleavage of a C−C Bond of Alkyl Phenyl Ketones
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Ruthenium(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes via Directed C–H Functionalization
TL;DR: The ruthenium-catalyzed hydroarylation of alkynes with benzamides proceeds regioselectively through a directed C-H bond cleavage, and preliminary mechanistic investigations indicate that the reaction involves amide-directed ortho-metalation, carbometalation of alkyne, and protonolysis.
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The Ru(cod)(cot)-catalyzed alkenylation of aromatic C-H bonds with alkenyl acetates.
TL;DR: This directAlkenylation of aromatic C−H bonds with alkenyl acetates provides π-conjugated aromatic and heteroaromatic compounds under halogen-free reaction conditions.
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Chain-Walking Strategy for Organic Synthesis: Catalytic Cycloisomerization of 1,n-Dienes
TL;DR: The use of chain walking provides a new method in organic synthesis to functionalize unreactive carbon-hydrogen bonds by letting the catalyst look for preferable bond-forming sites by moving around on the substrate.