F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
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Journal ArticleDOI
Direct carbonylation at a C-H bond in the benzene ring of 2- phenyloxazolines catalyzed by Ru3(CO)12. Scope, limitations, and mechanistic aspects
Yutaka Ie,Naoto Chatani,Takashi Ogo,Daniel Richard Marshall,Daniel Richard Marshall,Takahide Fukuyama,Fumitoshi Kakiuchi,Shinji Murai +7 more
TL;DR: The ruthenium-catalyzed carbonylation at a C-H bond in the benzene ring of a 2-phenyloxazoline is described and the results of deuterium labeling experiments suggest that the catalysis involves a reversible C- H bond cleavage and that the rate-determining step is not the cleavage of a C.H bond.
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Direct Alkenylation of Allylbenzenes via Chelation-Assisted C–C Bond Cleavage
TL;DR: A novel method for direct transformation of allyl groups in allylbenzene derivatives to alkenyl groups via rhodium-catalyzed C-C bond cleavage is reported and a new protocol for transformation of an ortho-prenylated phenol to an aniline derivative is developed.
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Iron-Catalyzed Regioselective Anti-Markovnikov Addition of C–H Bonds in Aromatic Ketones to Alkenes
TL;DR: A C-H alkylation reaction, in which the coupling of aromatic ketones with alkenes proceeds in the presence of only a simple Fe(PMe3)4 catalyst, with excellent regioselectivity under relatively mild reaction conditions.
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Mechanistic Study of the Ru(H)2(CO)(PPh3)3-Catalyzed Addition of C–H Bonds in Aromatic Esters to Olefins
TL;DR: In this paper, the reaction mechanism of the Ru(H)2(CO)(PPh3)3-catalyzed addition of C-H bonds in aromatic esters to olefins was studied by means of deuterium-labeling experiments and measurement of the 13C kinetic isotope effect.
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Ruthenium-Catalyzed Coupling of Aromatic Carbon-Hydrogen Bonds in Aromatic Imidates with Olefins
TL;DR: In this paper, the Ru3(CO)12-catalyzed reaction of 4,4-dimethyl-2-(2-methylphenyl)-5,6-dihydro-4H-1,3-oxazine with triethoxyvinylsilane gave a mixture of the corresponding 1:1 addition product (3a) and its olefinic analogue (3b) in good yields in ca a 1: 1 ratio.