F
Fumitoshi Kakiuchi
Researcher at Keio University
Publications - 235
Citations - 12426
Fumitoshi Kakiuchi is an academic researcher from Keio University. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 56, co-authored 230 publications receiving 11505 citations. Previous affiliations of Fumitoshi Kakiuchi include National Presto Industries & Kagawa University.
Papers
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Journal ArticleDOI
Ruthenium-Catalyzed Acylation of Arylpyridines with Acyl Chlorides via ortho-Selective C—H Bond Cleavage.
TL;DR: Ruthenium-catalyzed ortho-selective acylation of arylpyridines with acyl chlorides via C-H bond cleavage is described in this paper.
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Ruthenium‐Catalyzed Coupling of Aromatic Carbon—Hydrogen Bonds in Aromatic Imidates with Olefins.
TL;DR: In this article, the Ru3(CO)12-catalyzed reaction of 4,4-dimethyl-2-(2-methylphenyl)-5,6-dihydro-4H-1,3-oxazine (1) with triethoxyvinylsilane gave a mixture of the corresponding 1:1 addition product (3a) and its olefinic analogue (3b) in good yields in ca.
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A New Synthetic Route to Heteroarylsilanes via Ruthenium‐Catalyzed C—H/SiR3 Coupling.
Fumitoshi Kakiuchi,Mitsutaka Matsumoto,Motohiro Sonoda,Takahide Fukuyama,Naoto Chatani,Shinji Murai,Naoyuki Furukawa,Yoshio Seki +7 more
TL;DR: In this paper, a variety of heteroaromatic compounds can be used in this C-H/SiR3 coupling, e.g., ketone, ester, and amide.
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Rhodium‐Catalyzed C‐H—CO—Olefin Coupling Reactions — A Chelation‐Assisted Direct Carbonylation at the ortho C—H Bond in the Benzene Ring of 2‐Arylpyridines.
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Ruthenium‐Catalyzed ortho‐Selective Aromatic C—H Alkenylation with Alkenyl Carbonates.
TL;DR: The title reaction of aromatic compounds gives regioselectively alkenylated products as mentioned in this paper, whereas, on using harsh refluxing conditions, the corresponding alkylation product becomes the major product.