G
Gregory S. Sauer
Researcher at Cornell University
Publications - 7
Citations - 1416
Gregory S. Sauer is an academic researcher from Cornell University. The author has contributed to research in topics: Catalysis & Chemoselectivity. The author has an hindex of 7, co-authored 7 publications receiving 1068 citations.
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Journal ArticleDOI
Metal-catalyzed electrochemical diazidation of alkenes
TL;DR: An operationally simple and environmentally friendly protocol that converts alkenes and sodium azide—both readily available feedstocks—to 1,2-diazides and can be smoothly reduced to vicinal diamines in a single step, with high chemoselectivity.
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An Electrocatalytic Approach to the Radical Difunctionalization of Alkenes
Gregory S. Sauer,Song Lin +1 more
TL;DR: In this article, the design principles underpinning the development of electrochemical diazidation, dichlorination, and halotrifluoromethylation of alkenes were described.
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Anodically Coupled Electrolysis for the Heterodifunctionalization of Alkenes
Ke-Yin Ye,Gisselle Pombar,Gisselle Pombar,Niankai Fu,Gregory S. Sauer,Ivan Keresztes,Song Lin +6 more
TL;DR: The strategic use of anodically coupled electrolysis, an electrochemical process that combines two parallel oxidative events, as a complementary approach to existing methods for redox organic transformations is discussed.
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Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources
TL;DR: Mechanistic data are consistent with metal-mediated Cl atom transfer as the predominant pathway enabling dual C-Cl bond formation and contradict an alternative pathway involving electrochemical evolution of chlorine gas followed by Cl2-mediated electrophilic dichlorination.
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Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO-N3 Charge-Transfer Complex.
Juno C. Siu,Gregory S. Sauer,Ambarneil Saha,Reed L. Macey,Niankai Fu,Timothée Chauviré,Kyle M. Lancaster,Song Lin +7 more
TL;DR: A mild and efficient electrochemical protocol to access a variety of vicinally C-O and C-N difunctionalized compounds from simple alkenes and reveals a new reaction pathway mediated by the TEMPO+/TEMPO• redox couple that may expand the scope of aminoxyl radical chemistry in synthetic contexts.