Devices that show a magnetic anisotropy normal to the film surface hold great promise towards faster and smaller magnetic bits in data-storage applications. We describe an experimental demonstration of current-induced magnetic reversal of nanopillars with perpendicular anisotropy and high coercive fields. The best results are observed for Co/Ni multilayers, which have higher giant magnetoresistance values and spin-torque efficiencies than Co/Pt multilayers. The reference layers were designed to have significantly higher anisotropy allowing a complete current-field phase diagram of the free-layer reversal to be explored. The results are compared to micromagnetic modelling of the free layer that, depending on the bias current and applied field, details regions of irreversible magnetic switching, coherent and incoherent spin waves, or static non-uniform magnetization states. This ability to manipulate high-anisotropy magnetic elements could prove useful for a range of spintronic applications.

/pdf/current-induced-magnetization-reversal-in-nanopillars-with-29b9pmkqv5.pdf

Current-induced magnetization reversal in nanopillars with perpendicular anisotropy

Methods to pattern substrates with dense periodic nanostructures that combine top-down lithographic tools and self-assembling block copolymer materials are provided. According to various embodiments, the methods involve chemically patterning a substrate, depositing a block copolymer film on the chemically patterned imaging layer, and allowing the block copolymer to self-assemble in the presence of the chemically patterned substrate, thereby producing a pattern in the block copolymer film that is improved over the substrate pattern in terms feature size, shape, and uniformity, as well as regular spacing between arrays of features and between the features within each array compared to the substrate pattern. In certain embodiments, the density and total number of pattern features in the block copolymer film is also increased. High density and quality nanoimprint templates and other nanopatterned structures are also provided.

https://science.sciencemag.org/content/sci/321/5891/936.full.pdf

Density multiplication and improved lithography by directed block copolymer assembly

Nanofabrication of magnetic storage media, where servo marks, discrete tracks or individual islands are defined, offer the prospect for improved performance and increased areal density. However, this increase in performance will require that new and additional processes be introduced into disk manufacturing. We review here the fundamental patterning and fabrication processes that have been proposed, along with their respective strengths and weaknesses and the potential advantages they may offer for magnetic recording. The increase in data density afforded by nanofabrication may have added significance as more conventional approaches to ever increasing density will encounter physical limitations set by the thermal stability of the recorded bits.

https://iopscience.iop.org/article/10.1088/0022-3727/38/12/R01/pdf

Nanofabricated and self-assembled magnetic structures as data storage media

Chemically powered micro- and nanomotors are small devices that are self-propelled by catalytic reactions in fluids. Taking inspiration from biomotors, scientists are aiming to find the best architecture for self-propulsion, understand the mechanisms of motion, and develop accurate control over the motion. Remotely guided nanomotors can transport cargo to desired targets, drill into biomaterials, sense their environment, mix or pump fluids, and clean polluted water. This Review summarizes the major advances in the growing field of catalytic nanomotors, which started ten years ago.

Chemically Powered Micro- and Nanomotors

Nanoparticulate functional materials offer manifold perspectives for the increasing miniaturization and complexity of technical developments. Nanoparticles also make a major contribution to utilization of materials that is sparing of natural resources. Besides these obvious aspects, however, the importance of nanoparticles is due to their fundamentally novel properties and functions. These include photonic crystals and efficient luminophors, single particles and thin films for electronic storage media and switching elements, magnetic fluids and highly selective catalysts, a wide variety of possibilities for surface treatments, novel materials and concepts for energy conversion and storage, contrast agents for molecular biology and medical diagnosis, and fundamentally novel forms and structures of materials, such as nanocontainers and supercrystals. Creating high-quality nanoparticles requires that numerous parameters, involving the particle core and surface, colloidal properties, and particle deposition, are taken into consideration during synthesis of the material. An appropriate characterization and evaluation of the properties requires the incorporation of a wide range of expertise from widely differing areas. These circumstances are what challenges and appeals to the nanoscientist.

Nanoparticulate functional materials.

Thin-film technology is widely implemented in numerous applications1. Although flat substrates are commonly used, we report on the advantages of using curved surfaces as a substrate. The curvature induces a lateral film-thickness variation that allows alteration of the properties of the deposited material2,3. Based on this concept, a variety of implementations in materials science can be expected. As an example, a topographic pattern formed of spherical nanoparticles4,5 is combined with magnetic multilayer film deposition. Here we show that this combination leads to a new class of magnetic material with a unique combination of remarkable properties: The so-formed nanostructures are monodisperse, magnetically isolated, single-domain, and reveal a uniform magnetic anisotropy with an unexpected switching behaviour induced by their spherical shape. Furthermore, changing the deposition angle with respect to the particle ensemble allows tailoring of the orientation of the magnetic anisotropy, which results in tilted nanostructure material.

/pdf/magnetic-multilayers-on-nanospheres-2lvyo3gub5.pdf

Magnetic multilayers on nanospheres

The deposition of Co/Pd multilayer films onto self-assembled particle arrays with particle sizes down to 50 nm leads to pronounced curvature-induced physical properties. Unlike in classical nanosystems, the so-formed single caps on top of the spherical particles exhibit a radial symmetric anisotropy orientation across their surface. Its impact on the magnetization reversal process was analyzed experimentally for different particle sizes and compared to micromagnetic simulations, offering new opportunities in the functionalization of magnetic nanostructures.

Magnetization reversal in a novel gradient nanomaterial.

An approach to increasing the data storage density of magnetic recording was investigated wherein dot arrays are combined with multiple magnetic storage layers. The latter consists of two magnetically decoupled perpendicular Co∕Pd multilayer stacks. As a result of the difference in the coercivity between the two stacks, the orientation of the remanent magnetization of each stack can be set independent of the orientation of the other layer. Therefore, each dot allows storing four different magnetization states, which give rise to four different readback signal levels. Thus, the investigated media structure allows doubling the storage density in magnetic recording applications. It was found that even for thick spacer layers a weak magnetostatic coupling of the storage layers is present preferring ferromagnetic alignment of the storage layers.

Magnetic dot arrays with multiple storage layers

A patterned perpendicular magnetic recording medium has magnetic islands that contain stacks of individual magnetic cells to provide multilevel recording. Each cell in an island is formed of a material or set of materials to provide the cell with perpendicular magnetic anisotropy and is a single magnetic domain. Each cell is magnetically decoupled from the other cells in its island by nonmagnetic spacer layers. Thus each cell can have a magnetization (magnetic moment) in one of two directions (into or out of the plane of the layer making up the cell), and this magnetization is independent of the magnetization of the other cells in its island. This permits multiple magnetic levels or states to be recorded in each magnetic island.

Patterned multilevel perpendicular magnetic recording media

Magnetically isolated single domain islands with perpendicular anisotropy have been prepared by depositing Co/Pd multilayer films on prepatterned sub-50 nm SiO2/Si islands. The island arrays were fabricated by both direct write electron beam lithography and nanoimprinting. Nanoimprinting allows the creation of large area, 4 mm×4 mm, samples appropriate for characterization by conventional measurement techniques. Magnetic force microscopy and vibrating sample magnetometry showed that the reversal behavior of the patterned islands is quite different from that of the continuous films with a large increase in both switching field and switching field distribution. Recording on island arrays with a periodicity of 100 nm, produced from prepatterned substrates, was demonstrated using a quasistatic tester.

Guohan Hu

Papers

Magnetic multilayers on nanospheres

Magnetization reversal in a novel gradient nanomaterial.

Magnetic dot arrays with multiple storage layers

Patterned multilevel perpendicular magnetic recording media

Magnetic and recording properties of Co/Pd islands on prepatterned substrates