Metals have been mankind's most essential materials for thousands of years; however, their use is affected by ecological and economical concerns Alloys with higher strength and ductility could alleviate some of these concerns by reducing weight and improving energy efficiency However, most metallurgical mechanisms for increasing strength lead to ductility loss, an effect referred to as the strength-ductility trade-off Here we present a metastability-engineering strategy in which we design nanostructured, bulk high-entropy alloys with multiple compositionally equivalent high-entropy phases High-entropy alloys were originally proposed to benefit from phase stabilization through entropy maximization Yet here, motivated by recent work that relaxes the strict restrictions on high-entropy alloy compositions by demonstrating the weakness of this connection, the concept is overturned We decrease phase stability to achieve two key benefits: interface hardening due to a dual-phase microstructure (resulting from reduced thermal stability of the high-temperature phase); and transformation-induced hardening (resulting from the reduced mechanical stability of the room-temperature phase) This combines the best of two worlds: extensive hardening due to the decreased phase stability known from advanced steels and massive solid-solution strengthening of high-entropy alloys In our transformation-induced plasticity-assisted, dual-phase high-entropy alloy (TRIP-DP-HEA), these two contributions lead respectively to enhanced trans-grain and inter-grain slip resistance, and hence, increased strength Moreover, the increased strain hardening capacity that is enabled by dislocation hardening of the stable phase and transformation-induced hardening of the metastable phase produces increased ductility This combined increase in strength and ductility distinguishes the TRIP-DP-HEA alloy from other recently developed structural materials This metastability-engineering strategy should thus usefully guide design in the near-infinite compositional space of high-entropy alloys

Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off

Bonding mechanism in cold gas spraying

Welding Metallurgy of

Development of a generalized parameter window for cold spray deposition

One-dimensional carbon nanotubes and two-dimensional graphene nanosheets with unique electrical, mechanical and thermal properties are attractive reinforcements for fabricating light weight, high strength and high performance metal-matrix composites. Rapid advances of nanotechnology in recent years enable the development of advanced metal matrix nanocomposites for structural engineering and functional device applications. This review focuses on the recent development in the synthesis, property characterization and application of aluminum, magnesium, and transition metal-based composites reinforced with carbon nanotubes and graphene nanosheets. These include processing strategies of carbonaceous nanomaterials and their composites, mechanical and tribological responses, corrosion, electrical and thermal properties as well as hydrogen storage and electrocatalytic behaviors. The effects of nanomaterial dispersion in the metal matrix and the formation of interfacial precipitates on these properties are also addressed. Particular attention is paid to the fundamentals and the structure–property relationships of such novel nanocomposites.

Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets

https://bura.brunel.ac.uk/bitstream/2438/13101/1/FullText.pdf

Cold spraying - A materials perspective

In conventional thermal spraying, the spray particles are partially or fully molten when they deposit on the substrate. Cold spraying, in contrast, uses less thermal and more kinetic energy. In this process, solid particles impact on the substrate at high velocities and form excellent coatings. Due to comparatively low temperatures and typically inert process gases, cold spraying is particularly suitable for heat and oxidation sensitive materials. In recent years, modeling and computational methods have been widely used to study this relatively new spraying process, particularly to describe impact conditions of particles, to improve nozzle design, and to provide a better understanding of the thermo-mechanical processes that lead to particle bonding and deposition. This paper summarizes the state of the art in these theoretical studies, alongside a comprehensive description of the process. The paper also discusses the prediction of coating properties in the light of modeling combined with experimental investigations.

/pdf/from-particle-acceleration-to-impact-and-bonding-in-cold-ltb5c2psl2.pdf

From Particle Acceleration to Impact and Bonding in Cold Spraying

For cold spraying, a method for the construction of the window of deposition and the selection of optimum process parameters is presented. Initially, particle impact velocity and the critical particle velocity for bonding are worked out and expressed explicitly in terms of key process and material parameters. Subsequently, the influence of particle velocity on coating characteristics is examined in view of the results of experiments and simulations. It has been found that main coating characteristics can be described as a unique function of the ratio of particle velocity to critical velocity, here referred to as η. Finally, coating properties are linked directly to primary process parameters via parameter selection maps, where contours of constant η are plotted on a plane of gas temperature versus gas pressure. Inferences of the presented method and the resulting parameter selection maps are discussed for the example of copper as feedstock material.

/pdf/on-parameter-selection-in-cold-spraying-pp9ux3rf58.pdf

Hamid Assadi

Papers

Bonding mechanism in cold gas spraying

Development of a generalized parameter window for cold spray deposition

Cold spraying - A materials perspective

From Particle Acceleration to Impact and Bonding in Cold Spraying

On Parameter Selection in Cold Spraying