H
Haolin Yin
Researcher at University of Pennsylvania
Publications - 24
Citations - 1910
Haolin Yin is an academic researcher from University of Pennsylvania. The author has contributed to research in topics: Aryl & Catalysis. The author has an hindex of 16, co-authored 22 publications receiving 1546 citations.
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Journal ArticleDOI
Inside Cover: Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Aryl Iodides to Enals (Angew. Chem. Int. Ed. 1/2020)
Journal ArticleDOI
Innentitelbild: Synergistic N‑Heterocyclic Carbene/Palladium‑Catalyzed Umpolung 1,4‑Addition of Aryl Iodides to Enals (Angew. Chem. 1/2020)
Journal ArticleDOI
NiXantphos: a deprotonatable ligand for room-temperature palladium-catalyzed cross-couplings of aryl chlorides
Jiadi Zhang,Ana Bellomo,Nisalak Trongsiriwat,Tiezheng Jia,Patrick J. Carroll,Spencer D. Dreher,Matthew T. Tudge,Haolin Yin,Jerome R. Robinson,Eric J. Schelter,Patrick J. Walsh +10 more
TL;DR: Surprisingly, comparison of an extensive array of ligands revealed that under the basic reaction conditions the resultant heterobimetallic Pd–NiXantphos catalyst system outperformed all the other mono- and bidentate ligands in a deprotonative cross-coupling process (DCCP) with aryl chlorides.
Journal ArticleDOI
Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions.
TL;DR: The strongly reducing metalloradical character of 1, 1-(i)Pr, and 1-Cy in their (2)A1 excited states afforded photochemical halogen atom abstraction reactions from sp(3) and sp(2) C-X (X = Cl, Br, I) bonds for the first time with a lanthanide cation.
Journal ArticleDOI
Cerium Photosensitizers: Structure-Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions.
TL;DR: The photochemistry of the sterically congested complex 4 was demonstrated by C-C bond forming reaction between 4-fluoroiodobenzene and benzene through an outer sphere electron transfer pathway, which expands the capabilities of cerium photosensitizers beyond the previous results that demonstrated inner sphere halogen atom abstraction reactivity by 1-N.