Jacqueline Vaissermann

TL;DR: In this article, the use of a localized electron orbital model allowed the authors to push the Curie temperatures from 5.6 K to above room temperature in a vanadium-chromium Prussian blue analogue.

TL;DR: In this paper, the design and preparation of stable cyanide-bearing six-coordinate complexes of formula [MIII(L)(CN)x](x+l−−m)− (M = trivalent transition metal ion and L = polydentate blocking ligand) are summarized and the appropriate choice of the end-cap ligand L whose denticity determines the number of coordinated cyanide groups in the mononuclear precursors.

TL;DR: The molecular modelling study provides some clues for understanding of the antagonist effect of these molecules, while an additional cytotoxic effect due to the vectorised ferrocenyl unit is revealed in some occasions.

TL;DR: This finding prompted us to look carefully at 1D systems containing anisotropic elements, such as cobalt and low-spin iron centers that the authors synthesized recently, and opened the perspective of a potential use of 1D magnetic molecular nanowires for information storage.

TL;DR: DFT-type calculations and QMC methodology provided a good understanding of the magnetic properties of 3-5, which are ferro- and ferrimagnetic chains respectively, with metamagnetic-like behavior.