Fujishima and Honda (1972) demonstrated the potential of titanium dioxide (TiO2) semiconductor materials to split water into hydrogen and oxygen in a photo-electrochemical cell. Their work triggered the development of semiconductor photocatalysis for a wide range of environmental and energy applications. One of the most significant scientific and commercial advances to date has been the development of visible light active (VLA) TiO2 photocatalytic materials. In this review, a background on TiO2 structure, properties and electronic properties in photocatalysis is presented. The development of different strategies to modify TiO2 for the utilization of visible light, including non metal and/or metal doping, dye sensitization and coupling semiconductors are discussed. Emphasis is given to the origin of visible light absorption and the reactive oxygen species generated, deduced by physicochemical and photoelectrochemical methods. Various applications of VLA TiO2, in terms of environmental remediation and in particular water treatment, disinfection and air purification, are illustrated. Comprehensive studies on the photocatalytic degradation of contaminants of emerging concern, including endocrine disrupting compounds, pharmaceuticals, pesticides, cyanotoxins and volatile organic compounds, with VLA TiO2 are discussed and compared to conventional UV-activated TiO2 nanomaterials. Recent advances in bacterial disinfection using VLA TiO2 are also reviewed. Issues concerning test protocols for real visible light activity and photocatalytic efficiencies with different light sources have been highlighted.

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A review on the visible light active titanium dioxide photocatalysts for environmental applications

An introduction to heat transfer

Author(s): Vogel, Alfred; Venugopalan, Vasan | Abstract: The mechanisms of pulsed laser ablation of biological tissues were studied. The transiently empty space created between the fiber tip and the tissue surface improved the optical transmission to the target and thus increased the ablation efficiency. It was found that the structure and morphology also affect the energy transport among tissue constituents.

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Mechanisms of pulsed laser ablation of biological tissues.

Nanofluids are potential heat transfer fluids with enhanced thermophysical properties and heat transfer performance can be applied in many devices for better performances (i.e. energy, heat transfer and other performances). In this paper, a comprehensive literature on the applications and challenges of nanofluids have been compiled and reviewed. Latest up to date literatures on the applications and challenges in terms of PhD and Master thesis, journal articles, conference proceedings, reports and web materials have been reviewed and reported. Recent researches have indicated that substitution of conventional coolants by nanofluids appears promising. Specific application of nanofluids in engine cooling, solar water heating, cooling of electronics, cooling of transformer oil, improving diesel generator efficiency, cooling of heat exchanging devices, improving heat transfer efficiency of chillers, domestic refrigerator-freezers, cooling in machining, in nuclear reactor and defense and space have been reviewed and presented. Authors also critically analyzed some of the applications and identified research gaps for further research. Moreover, challenges and future directions of applications of nanofluids have been reviewed and presented in this paper. Based on results available in the literatures, it has been found nanofluids have a much higher and strongly temperature-dependent thermal conductivity at very low particle concentrations than conventional fluids. This can be considered as one of the key parameters for enhanced performances for many of the applications of nanofluids. Because of its superior thermal performances, latest up to date literatures on this property have been summarized and presented in this paper as well. However, few barriers and challenges that have been identified in this review must be addressed carefully before it can be fully implemented in the industrial applications.

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A review on applications and challenges of nanofluids

EDDINGTON'S “Internal Constitution of the Stars” was published in 1926 and gives what now ranks as a classical account of his own researches and of the general state of the theory at that time. Since then, a tremendous amount of work has appeared. Much of it has to do with the construction of stellar models with different equations of state applying in different zones. Other parts deal with the effects of varying chemical composition, with pulsation and tidal and rotational distortion of stars, and with the precise relations between the interior and the atmosphere of a star. The striking feature of all this work is that so much can be done without assuming any particular mechanism of stellar energy-generation. Only such very comprehensive assumptions are made about the distribution and behaviour of the energy sources that we may expect future knowledge of their mechanism to lead mainly to more detailed results within the framework of the existing general theory. An Introduction to the Study of Stellar Structure By S. Chandrasekhar. (Astrophysical Monographs sponsored by The Astrophysical Journal.) Pp. ix+509. (Chicago: University of Chicago Press; London: Cambridge University Press, 1939.) 50s. net.

Ho-Young Kwak

Papers

Forced convective heat transfer of nanofluids in microchannels

Exergetic and thermoeconomic analyses of power plants

Exergoeconomic analysis of thermal systems

Exergoeconomic analysis of gas turbine cogeneration systems

Catalytic test of supported Ni catalysts with core/shell structure for dry reforming of methane