다중혈관 관상동맥 환자에서 y-문합을 이용하여 양쪽 내흉동맥만을 사용한 우회술의 조기 성적

[신간의 별자리x] 우리/미술, 그리고 ‘슬픔의 박물관’

Low-temperature solution-processed photovoltaics suffer from low efficiencies because of poor exciton or electron-hole diffusion lengths (typically about 10 nanometers). Recent reports of highly efficient CH3NH3PbI3-based solar cells in a broad range of configurations raise a compelling case for understanding the fundamental photophysical mechanisms in these materials. By applying femtosecond transient optical spectroscopy to bilayers that interface this perovskite with either selective-electron or selective-hole extraction materials, we have uncovered concrete evidence of balanced long-range electron-hole diffusion lengths of at least 100 nanometers in solution-processed CH3NH3PbI3. The high photoconversion efficiencies of these systems stem from the comparable optical absorption length and charge-carrier diffusion lengths, transcending the traditional constraints of solution-processed semiconductors.

https://dr.ntu.edu.sg/bitstream/10220/16761/1/long-range balanced electron- and hole-transport lengths in organic-inorganic ch3nh3pbi3.pdf

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3

There is still an ongoing effort to search for sustainable, clean and highly efficient energy generation to satisfy the energy needs of modern society. Among various advanced technologies, electrocatalysis for the oxygen evolution reaction (OER) plays a key role and numerous new electrocatalysts have been developed to improve the efficiency of gas evolution. Along the way, enormous effort has been devoted to finding high-performance electrocatalysts, which has also stimulated the invention of new techniques to investigate the properties of materials or the fundamental mechanism of the OER. This accumulated knowledge not only establishes the foundation of the mechanism of the OER, but also points out the important criteria for a good electrocatalyst based on a variety of studies. Even though it may be difficult to include all cases, the aim of this review is to inspect the current progress and offer a comprehensive insight toward the OER. This review begins with examining the theoretical principles of electrode kinetics and some measurement criteria for achieving a fair evaluation among the catalysts. The second part of this review acquaints some materials for performing OER activity, in which the metal oxide materials build the basis of OER mechanism while non-oxide materials exhibit greatly promising performance toward overall water-splitting. Attention of this review is also paid to in situ approaches to electrocatalytic behavior during OER, and this information is crucial and can provide efficient strategies to design perfect electrocatalysts for OER. Finally, the OER mechanism from the perspective of both recent experimental and theoretical investigations is discussed, as well as probable strategies for improving OER performance with regards to future developments.

Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives

Since the discovery of mechanically exfoliated graphene in 2004, research on ultrathin two-dimensional (2D) nanomaterials has grown exponentially in the fields of condensed matter physics, material science, chemistry, and nanotechnology. Highlighting their compelling physical, chemical, electronic, and optical properties, as well as their various potential applications, in this Review, we summarize the state-of-art progress on the ultrathin 2D nanomaterials with a particular emphasis on their recent advances. First, we introduce the unique advances on ultrathin 2D nanomaterials, followed by the description of their composition and crystal structures. The assortments of their synthetic methods are then summarized, including insights on their advantages and limitations, alongside some recommendations on suitable characterization techniques. We also discuss in detail the utilization of these ultrathin 2D nanomaterials for wide ranges of potential applications among the electronics/optoelectronics, electrocat...

Recent Advances in Ultrathin Two-Dimensional Nanomaterials

In the quest for mass production of hydrogen from water electrolysis, to develop highly efficient, stable and low-cost catalysts is still the central challenge. When designing a novel catalyst, it is necessary to optimize the exposure and accessibility of its active sites as well as the reaction kinetics. This can be realized by combining an appropriate chemical composition of the material, including doping with metal elements, and a properly nanostructured morphology offering a high surface contact. We report here on the design and performances of cobalt-based oxide and sulfide nanowires as catalysts that can be used for both hydrogen and oxygen evolution reactions (denoted HER and OER respectively) in the same compatible electrolyte. Following a sulfuration process, Co3O4 nanowires are entirely converted into Co3S4 nanowires showing greatly improved OER catalytic performances with an overpotential of 283 mV (instead of 371 mV for Co3O4) to deliver a current density of 10 mA cm-2. Besides, when doping the surface of these Co3S4 nanowires with small amounts of nickel, the resulting Ni:Co3S4 nanowires exhibit an HER overpotential of 199 mV to reach 10 mA cm-2. But most importantly, two-electrode electrolyzer cells combining Co3S4 and Ni:Co3S4 electrodes show operating voltages as low as 1.70 V at 10 mA cm-2 over 40 hours, a value that competes advantageously with the best reported catalysts in 1.0 M KOH. Meanwhile, density functional theory (DFT) calculations show that the free energy of the intermediates has been reduced after the introduction of sulfur and nickel atoms, which have smaller overpotentials and corresponding enhanced electrocatalytic performance. Our results open a new avenue in the quest for overall water splitting using electrochemical systems.

Combining Co3S4 and Ni:Co3S4 nanowires as efficient catalysts for overall water splitting: an experimental and theoretical study.

A low-cost and one-step synthesis of N-doped monolithic quasi-graphene films with porous carbon frameworks for Li-ion batteries

Work function strongly impacts the surficial charge distribution, especially for metal-support electrocatalysts when a built-in electric field (BEF) is constructed. Therefore, studying the correlation between work function and BEF is crucial for understanding the intrinsic reaction mechanism. Herein, we present a Pt@CoO x electrocatalyst with a large work function difference (ΔΦ) and strong BEF, which shows outstanding hydrogen evolution activity in a neutral medium with a 4.5-fold mass activity higher than 20% Pt/C. Both experimental and theoretical results confirm the interfacial charge redistribution induced by the strong BEF, thus subtly optimizing hydrogen and hydroxide adsorption energy. This work not only provides fresh insights into the neutral hydrogen evolution mechanism but also proposes new design principles toward efficient electrocatalysts for hydrogen production in a neutral medium.

Modulating built-in electric field via variable oxygen affinity for robust hydrogen evolution reaction in neutral media.

/pdf/partial-nitridation-induced-electrochemistry-enhancement-of-m98khkbbsh.pdf

Partial Nitridation-Induced Electrochemistry Enhancement of Ternary Oxide Nanosheets for Fiber Energy Storage Device

https://dr.ntu.edu.sg/bitstream/10220/47856/1/Integration%20of%20Energy%20Harvesting%20and%20Electrochemical%20Storage%20Devices%20%281%29.pdf

Hong Jin Fan

Papers

Combining Co3S4 and Ni:Co3S4 nanowires as efficient catalysts for overall water splitting: an experimental and theoretical study.

A low-cost and one-step synthesis of N-doped monolithic quasi-graphene films with porous carbon frameworks for Li-ion batteries

Modulating built-in electric field via variable oxygen affinity for robust hydrogen evolution reaction in neutral media.

Partial Nitridation-Induced Electrochemistry Enhancement of Ternary Oxide Nanosheets for Fiber Energy Storage Device

Integration of Energy Harvesting and Electrochemical Storage Devices