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Jacob H. Olshansky

Researcher at Northwestern University

Publications -  27
Citations -  1187

Jacob H. Olshansky is an academic researcher from Northwestern University. The author has contributed to research in topics: Quantum dot & Quantum yield. The author has an hindex of 13, co-authored 23 publications receiving 852 citations. Previous affiliations of Jacob H. Olshansky include Lawrence Berkeley National Laboratory & University of California, Berkeley.

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Design Principles for Trap-Free CsPbX3 Nanocrystals: Enumerating and Eliminating Surface Halide Vacancies with Softer Lewis Bases.

TL;DR: This work provides a systematic framework for preparing highly luminescent CsPbX3 nanocrystals with variable compositions and dimensionalities, thereby improving the fundamental understanding of these materials and informing future synthetic and post-synthetic efforts toward trap-free CspbX2 nanocrystal efforts.
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Efficiency of hole transfer from photoexcited quantum dots to covalently linked molecular species.

TL;DR: The results show the potential of QD systems to drive desirable oxidative chemistry without undergoing oxidative photodegradation, and the merits of a system where ill-defined nonradiative channels are suppressed and well-definedNonradiatives channels are engineered and quantified are demonstrated.
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Surface- vs Diffusion-Limited Mechanisms of Anion Exchange in CsPbBr3 Nanocrystal Cubes Revealed through Kinetic Studies

TL;DR: These results represent the first steps toward developing a microkinetic description of the anion exchange, with implications not only for understanding the lead halide perovskites but also for nanoscale ion exchange in general.
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Hole Transfer from Photoexcited Quantum Dots: The Relationship between Driving Force and Rate.

TL;DR: The observed relationship between driving force and rate for interfacial hole transfer from quantum dots (QDs) can be used to design QD-molecular systems that maximize interfacial charge transfer rates while minimizing energetic losses associated with the driving force.
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Hole Transfer Dynamics from a CdSe/CdS Quantum Rod to a Tethered Ferrocene Derivative

TL;DR: Hole transfer between a CdSe/CdS core/shell semiconductor nanorod and a surface-ligated alkyl ferrocene and the results suggest that holes may be extracted more efficiently from well-passivated nanocrystals by reducing the energetic driving force for hole transfer, thus minimizing energetic losses.