J
Jason A. Mulder
Researcher at Boehringer Ingelheim
Publications - 64
Citations - 1913
Jason A. Mulder is an academic researcher from Boehringer Ingelheim. The author has contributed to research in topics: Propargyl & Enantioselective synthesis. The author has an hindex of 22, co-authored 63 publications receiving 1791 citations. Previous affiliations of Jason A. Mulder include Harvard University & University of Wisconsin-Madison.
Papers
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Journal ArticleDOI
Recent advances in the chemistry of ynamines and ynamides
Journal ArticleDOI
A copper-catalyzed C-N bond formation involving sp-hybridized carbons. A direct entry to chiral ynamides via N-alkynylation of amides.
Michael O. Frederick,Jason A. Mulder,Michael R. Tracey,Richard P. Hsung,Jian Huang,Kimberly C. M. Kurtz,Lichun Shen,Christopher J. Douglas +7 more
TL;DR: A copper-catalyzed new C-N bond formation involving a sp-hybridized carbon is described here leading to a facile entry for syntheses of chiral ynamides, which should have a significant impact on the future development of synthetic methodologies employing ynamide.
Journal ArticleDOI
Highly stereoselective synthesis of novel alpha-haloenamides via a mild and efficient hydrohalogenation of ynamides.
Jason A. Mulder,Kimberly C. M. Kurtz,Richard P. Hsung,Heather A. Coverdale,Michael O. Frederick,Lichun Shen,Craig A. Zificsak +6 more
TL;DR: A highly stereoselective preparation of novel chiral (E)-alpha-haloenamides under mild conditions utilizing magnesium halide salts is described, highlighting another synthetic utility of ynamides.
Journal ArticleDOI
Molecular Assemblies on Silicon Surfaces via Si−O Linkages
TL;DR: In this paper, a two-step strategy for monolayer assembly on silicon surfaces is presented, in which a H-terminated Si(100) or Si(111) surface reacts with Cl2 to give a Cl-capped surface.
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The first successful base-promoted isomerization of propargyl amides to chiral ynamides. Applications in ring-closing metathesis of ene-ynamides and tandem RCM of diene-ynamides.
TL;DR: These reactions consist of the first successful base-induced isomerizations of propargyl amides to chiral ynamide, applications of these novel ynamides in ring-closure metathesis leading to chirpy 2-amidodienes useful for Diels-Alder cycloadditions, and the first successfully tandem RCM of diene-ynamides.