J
Jay Agarwal
Researcher at University of Georgia
Publications - 37
Citations - 1190
Jay Agarwal is an academic researcher from University of Georgia. The author has contributed to research in topics: Coupled cluster & Potential energy surface. The author has an hindex of 16, co-authored 37 publications receiving 1035 citations. Previous affiliations of Jay Agarwal include Brookhaven National Laboratory.
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Journal ArticleDOI
Mechanisms for CO production from CO2 using reduced rhenium tricarbonyl catalysts.
TL;DR: The mechanism for carbon monoxide production using rhenium tricarbonyl catalysts has been investigated using density functional theory and structures and energies for the proposed reaction path are presented and compared to previously published experimental observations.
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NHC‐Containing Manganese(I) Electrocatalysts for the Two‐Electron Reduction of CO2
Jay Agarwal,Travis W. Shaw,Charles J. Stanton,George Majetich,Andrew Bruce Bocarsly,Henry F. Schaefer +5 more
TL;DR: The synthesis and characterization of the first catalytic manganese N-heterocyclic carbene complexes are reported, andCatalytic current enhancement is observed at voltages similar to MnBr(2,2'-bipyridine)(CO)3.
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Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3
TL;DR: Characterization by cyclic voltammetry and infrared spectroelectrochemistry indicates that the stability of the singly reduced [Mn(CN)(bpy)(CO)3](•-) differs slightly in the N,N-DMF-TEOA solvent system compared to the MeCN- TEOA system, which contributes to the observed selectivities for HCO2H vs CO production.
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Re(I) NHC Complexes for Electrocatalytic Conversion of CO2
Charles J. Stanton,Charles W. Machan,Jonathon E. Vandezande,Tong Jin,George Majetich,Henry F. Schaefer,Clifford P. Kubiak,Gonghu Li,Jay Agarwal +8 more
TL;DR: The modular construction of ligands around an N-heterocyclic carbene building block represents a flexible synthetic strategy for tuning the electronic properties of metal complexes and is shown to be capable of mediating the two-Electron conversion of CO2 following one-electron reduction.
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Electrocatalytic Reduction of Carbon Dioxide by Mn(CN)(2,2'-bipyridine)(CO)3: CN Coordination Alters Mechanism.
Charles W. Machan,Charles J. Stanton,Jonathon E. Vandezande,George Majetich,Henry F. Schaefer,Clifford P. Kubiak,Jay Agarwal +6 more
TL;DR: substitution of the axial bromide for a pseudohalogen (CN) is investigated, yielding Mn(CN)(2,2'-bipyridine)(CO)3, which arises from the disproportionation of two one-electron-reduced species to generate the catalytically active species.