Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

Phd by thesis

Metal-based additive manufacturing, or three-dimensional (3D) printing, is a potentially disruptive technology across multiple industries, including the aerospace, biomedical and automotive industries. Building up metal components layer by layer increases design freedom and manufacturing flexibility, thereby enabling complex geometries, increased product customization and shorter time to market, while eliminating traditional economy-of-scale constraints. However, currently only a few alloys, the most relevant being AlSi10Mg, TiAl6V4, CoCr and Inconel 718, can be reliably printed; the vast majority of the more than 5,500 alloys in use today cannot be additively manufactured because the melting and solidification dynamics during the printing process lead to intolerable microstructures with large columnar grains and periodic cracks. Here we demonstrate that these issues can be resolved by introducing nanoparticles of nucleants that control solidification during additive manufacturing. We selected the nucleants on the basis of crystallographic information and assembled them onto 7075 and 6061 series aluminium alloy powders. After functionalization with the nucleants, we found that these high-strength aluminium alloys, which were previously incompatible with additive manufacturing, could be processed successfully using selective laser melting. Crack-free, equiaxed (that is, with grains roughly equal in length, width and height), fine-grained microstructures were achieved, resulting in material strengths comparable to that of wrought material. Our approach to metal-based additive manufacturing is applicable to a wide range of alloys and can be implemented using a range of additive machines. It thus provides a foundation for broad industrial applicability, including where electron-beam melting or directed-energy-deposition techniques are used instead of selective laser melting, and will enable additive manufacturing of other alloy systems, such as non-weldable nickel superalloys and intermetallics. Furthermore, this technology could be used in conventional processing such as in joining, casting and injection moulding, in which solidification cracking and hot tearing are also common issues.

3D printing of high-strength aluminium alloys

Mechanical properties in the semi-solid state and hot tearing of aluminium alloys

Solidification microstructures and solid-state parallels: Recent developments, future directions

Nuclear Instruments and Methods in Physics Research. Section B; Microstructural Characterization of Semi-Interpenetrating Polymer Networks by Positron Lifetime Spectroscopy

A new criterion for the appearance of hot tears in metallic alloys is proposed. Based upon a mass balance performed over the liquid and solid phases, it accounts for the tensile deformation of the solid skeleton perpendicular to the growing dendrites and for the induced interdendritic liquid feeding. This model introduces a critical deformation rate (
 
$$\dot \varepsilon _{p,\max } $$

 ) beyond which cavitation, i.e., nucleation of a first void, occurs. As should be expected, this critical value is an increasing function of the thermal gradient and permeability and a decreasing function of the viscosity. The shrinkage contribution, which is also included in the model, is shown to be of the same order of magnitude as that associated with the tensile deformation of the solid skeleton. A hot-cracking sensitivity (HCS) index is then defined as 
$$\dot \varepsilon _{_{p,\max } }^{ - 1} $$

 . When applied to a variable-concentration aluminum-copper alloy, this HCS criterion can reproduce the typical “Λ curves” previously deduced by Clyne and Davies on a phenomenological basis. The calculated values are in fairly good agreement with those obtained experimentally by Spittle and Cushway for a non-grain-refined alloy. A comparison of this criterion to hot cracks observed in ring-mold solidification tests indicates cavitation depression of a few kilo Pascal and tensile stresses in the coherent mushy zone of a few mega Pascal. These values are discussed in terms of those obtained by other means (coherency measurement, microporosity observation, and simulation). Even though this HCS criterion is based only upon the appearance of a first void and not on its propagation, it sets up for the first time a physically sound basis for the study of hot-crack formation.

/pdf/a-new-hot-tearing-criterion-2z5ivwusns.pdf

A New Hot-Tearing Criterion

http://www.ansatt.hig.no/ivarf/publications/Farup_01_acta.pdf

In-situ Observation of Hot tearing Formation in Succinonitrile-Acetone

The rheological behavior of a solidifying alloy is modeled by considering the deforming material as a viscoplastic porous medium saturated with liquid. Since the solid grains in the mush do not form a fully cohesive skeleton, an internal variable that represents the partial cohesion of this porous material is introduced. The model parameters are identified using shear and compressive stress states under isothermal conditions on an Al-Cu model alloy. The model is partially validated with non-isothermal conditions and we complete this study with tensile conditions. Such conditions, when applied on the mush, may lead to severe defects in many casting processes. The model has been implemented into a commercial finite-element code to simulate a tensile test. Comparison with experimental data shows that the model is able to reproduce the main features of a solidifying alloy under tension, although fracture is not directly addressed here. We show that two critical solid fractions must be introduced in the model to account for the rheology: the coherency solid fraction at which the mush acquires significant strength and the coalescence solid fraction at which solid grains start to form solid bridges.

/pdf/rheological-behavior-of-al-cu-alloys-during-solidification-mpa03w3zyg.pdf

Rheological Behavior of Al-Cu Alloys during Solidification: Constitutive Modeling, Experimental Identification, and Numerical Study

In order to quantify the cooling conditions undergone by an ingot during direct-chill (DC) casting, thermocouples were immersed in the liquid pool and consequently entrapped in the solid, thus monitoring the temperature of the metal during its descent. Assuming steady-state thermal conditions, the time-dependent temperatures measured by these thermocouples were then converted into spacedependent temperature profiles. These values were the input of a Maximum A Posteriori (MAP) inverse method described by Rappaz et al.,[1] which has been adapted in this case to steady-state thermal conditions. This MAP method permits the deduction of the temperature-dependent thermal conductivity of the alloy, initially, and then of the highly nonuniform heat-flux distribution along the ingot rolling faces, in a second step. The obtained values are in good agreement with literature and clearly reflect the widely different boundary conditions associated with primary cooling (contact with the mold) and secondary cooling (water jet).

Determination of thermophysical properties and boundary conditions of direct chill-cast aluminum alloys using inverse methods

A comprehensive three-dimensional (3-D) mathematical model based upon the ABAQUS software has been developed for the computation of the thermomechanical state of the solidifying strand during direct chill (DC) casting of rolling sheet ingots and during subsequent cooling. Based upon a finiteelement formulation, the model determines the temperature distribution, the stresses, and the associated deformations in the metal. For that purpose, the thermomechanical properties of the alloy have been measured up to the coherency temperature using creep and indentation tests. The thermophysical properties as well as the boundary conditions associated with the lateral water spray have been determined using inverse modeling. The predicted ingot distortions, mainly, “butt curl,” “butt swell,” and lateral faces pull-in, are compared with experimental measurements performed during solidification and after complete cooling of the ingot. Particular emphasis is placed on the nonuniform contraction of the lateral faces. The influence of the mold shape and the contributions to this contraction are assessed as a function of the casting conditions.

/pdf/modeling-of-ingot-distortions-during-direct-chill-casting-of-15lshp6uyt.pdf

Jean-Marie Drezet

Papers

A New Hot-Tearing Criterion

In-situ Observation of Hot tearing Formation in Succinonitrile-Acetone

Rheological Behavior of Al-Cu Alloys during Solidification: Constitutive Modeling, Experimental Identification, and Numerical Study

Determination of thermophysical properties and boundary conditions of direct chill-cast aluminum alloys using inverse methods

Modeling of ingot distortions during direct chill casting of aluminum alloys