J
Juan J. Fiol
Researcher at University of the Balearic Islands
Publications - 70
Citations - 1388
Juan J. Fiol is an academic researcher from University of the Balearic Islands. The author has contributed to research in topics: Ligand & Hydrogen bond. The author has an hindex of 21, co-authored 69 publications receiving 1307 citations. Previous affiliations of Juan J. Fiol include Spanish National Research Council.
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Synthesis and characterization of a new Ni(II) pyrimidine complex. Crystal and molecular structure of trans-bis(isocytosine-O4) bis(ethylenediamine) Ni(II) bis(tetraphenylborate)
TL;DR: The lilac complex [Ni(en)2(isocyt)2][B(C6H5)4]2 (en=ethylenediamine; isocyt=isoctosine) has been prepared by reaction of [Ni[n 2Cl]2Cl2 and the pyrimidine base in ethanol-water medium as mentioned in this paper, which crystallizes in the triclinic space group P-1 with a=9.488(6), b=11.020(5), c=13.986(6) A,
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Structures of tetrachlorometalates [Zn(II) and Hg(II)] of trimethylene-bisadeninium
TL;DR: In this article, the X-ray structure of outer sphere complexes (H-Ade)2(CH2)3]ZnCl4·H2O 1 and H2O 2 is reported (Ade=adenine).
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Bioinorganic chemistry of copper(II) complexes of N-salicylidene-aminoacidato: associative versus dissociative mechanism in the formation of copper ternary complexes with 2-aminopyridine (or pyrimidine). An ab initio study
TL;DR: An ab initio computational study has been performed in order to evaluate the associative versus dissociative mechanism in the formation of ternary complexes of copper(II) N -salicylidene-aminoacidato with 2-aminopyridine (or pyrimidine).
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Metallation of Isatin(2,3-Indolinedione). X-Ray Structure and Solution Behavior ofBis(Isatinato)Mercury(II)
Angel García-Raso,Juan J. Fiol,Elies Molins,Antonia M. Calafat,Patricia A. Marzilli,Luigi G. Marzilli +5 more
TL;DR: The IR, electronic, and 1H and 13CNMR spectral data of (1), (2), and (3) suggest binding of the memury to the heterocyclic nitrogen, in agreement with the crystal structure determination.
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Ag(I) complexes with alkylidene-bis(2-aminopyrimidines) as building units for discrete metallomacrocyclic frames. A structural and solution study
Angel García-Raso,Juan J. Fiol,Andrés Tasada,Francisca M. Albertí,Elies Molins,Manuel G. Basallote,Marı́a A. Máñez,María J. Fernández-Trujillo,David Sánchez +8 more
TL;DR: Alkylidene-bis(2-aminopyrimidines) (pyr2Cx, x = 2-5) are useful ligands to interact with Ag(I) yielding discrete metallocycles and the solution study shows that the equilibrium constants for the formation of Ag(pyr 2Cx)+ complexes are higher than the literature values for Ag( I) complexes with single pyrimidine.