K
Kunihiko Fujii
Researcher at University of Tokyo
Publications - 5
Citations - 366
Kunihiko Fujii is an academic researcher from University of Tokyo. The author has contributed to research in topics: Enantioselective synthesis & Catalysis. The author has an hindex of 3, co-authored 5 publications receiving 349 citations.
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Journal ArticleDOI
A general catalytic allylation using allyltrimethoxysilane.
TL;DR: Preliminary extension of the reaction to the first catalytic enantioselective allylation of ketones using an allylsilane produced the product with 61% ee from acetophenone, using a CuCl-p-tol-BINAP-TBAT catalyst.
Journal ArticleDOI
Formal catalytic asymmetric total synthesis of fostriecin.
TL;DR: The common synthetic intermediate of a potent and promising anticancer agent, fostriecin, was synthesized using a unique method that combines four catalytic asymmetric reactions as shown above.
Journal ArticleDOI
Catalyst-controlled asymmetric synthesis of fostriecin and 8-epi-fostriecin.
Keisuke Maki,Rie Motoki,Kunihiko Fujii,Motomu Kanai,Takayasu Kobayashi,Shinri Tamura,Masakatsu Shibasaki +6 more
TL;DR: All the stereocenters were constructed under catalyst control in this synthesis and should be useful for rapid synthesis of stereoisomers of fostriecin.
Journal ArticleDOI
A General Catalytic Allylation Using Allyltrimethoxysilane.
TL;DR: In this paper, a mild catalytic allylation of carbonyl compounds, applicable to aldehydes, ketones, and imines, was developed using allyltrimethoxysilane as the allylating reagent.