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Showing papers by "Li Chen published in 2015"


Journal ArticleDOI
TL;DR: It is found that most of the values of correction factor fall in the slip and transition regime, with no Darcy flow regime observed, indicating Knudsen diffusion always plays a role on shale gas transport mechanisms in the reconstructed shales.
Abstract: Porous structures of shales are reconstructed using the markov chain monte carlo (MCMC) method based on scanning electron microscopy (SEM) images of shale samples from Sichuan Basin, China. Characterization analysis of the reconstructed shales is performed, including porosity, pore size distribution, specific surface area and pore connectivity. The lattice Boltzmann method (LBM) is adopted to simulate fluid flow and Knudsen diffusion within the reconstructed shales. Simulation results reveal that the tortuosity of the shales is much higher than that commonly employed in the Bruggeman equation, and such high tortuosity leads to extremely low intrinsic permeability. Correction of the intrinsic permeability is performed based on the dusty gas model (DGM) by considering the contribution of Knudsen diffusion to the total flow flux, resulting in apparent permeability. The correction factor over a range of Knudsen number and pressure is estimated and compared with empirical correlations in the literature. For the wide pressure range investigated, the correction factor is always greater than 1, indicating Knudsen diffusion always plays a role on shale gas transport mechanisms in the reconstructed shales. Specifically, we found that most of the values of correction factor fall in the slip and transition regime, with no Darcy flow regime observed.

282 citations


Journal ArticleDOI
TL;DR: In this paper, high-resolution porous structures of catalyst layers (CLs) including non-precious metal catalysts (NPMCs) or Pt for proton exchange membrane fuel cells are reconstructed using the quartet structure generation set.

108 citations


Journal ArticleDOI
TL;DR: In this paper, a pore-scale two-phase multi-mixture model based on the lattice Boltzmann method (LBM) is developed for such complex transport processes, where each phase is considered as a mixture of miscible components in it.

101 citations


Journal ArticleDOI
TL;DR: Simulations performed in a heterogeneous porous medium with components of different porosity and permeability indicate that Klinkenberg's effect plays a significant role on fluid flow in low-permeability porous media, and it is more pronounced as the Knudsen number increases.
Abstract: Gas slippage occurs when the mean free path of the gas molecules is in the order of the characteristic pore size of a porous medium. This phenomenon leads to Klinkenberg's effect where the measured permeability of a gas (apparent permeability) is higher than that of the liquid (intrinsic permeability). A generalized lattice Boltzmann model is proposed for flow through porous media that includes Klinkenberg's effect, which is based on the model of Guo et al. [Phys. Rev. E 65, 046308 (2002)]. The second-order Beskok and Karniadakis-Civan's correlation [A. Beskok and G. Karniadakis, Microscale Thermophys. Eng. 3, 43 (1999) and F. Civan, Transp. Porous Med. 82, 375 (2010)] is adopted to calculate the apparent permeability based on intrinsic permeability and the Knudsen number. Fluid flow between two parallel plates filled with porous media is simulated to validate the model. Simulations performed in a heterogeneous porous medium with components of different porosity and permeability indicate that Klinkenberg's effect plays a significant role on fluid flow in low-permeability porous media, and it is more pronounced as the Knudsen number increases. Fluid flow in a shale matrix with and without fractures is also studied, and it is found that the fractures greatly enhance the fluid flow and Klinkenberg's effect leads to higher global permeability of the shale matrix.

98 citations


Journal ArticleDOI
15 Nov 2015-Fuel
TL;DR: In this article, a representative elementary volume (REV)-scale structure of shale matrix is reconstructed based on elementary building block (EBB) model using a stochastic reconstruction method called Quartet Structure Generation Set.

91 citations


Journal ArticleDOI
15 Oct 2015-Fuel
TL;DR: In this article, a pore-scale model based on the lattice Boltzmann method developed in a previous study is used to predict the Knudsen diffusivity and permeability of the reconstructed organic matter.

65 citations


Journal ArticleDOI
TL;DR: Benefiting from the advantages of the LB method, both bulk and intraparticle mass transfer performances during adsorption can be obtained using the present pore scale approach.

54 citations


Journal ArticleDOI
TL;DR: In this paper, a thermal resistance network model was established and variable-height channels were proposed to improve the temperature uniformity on the heating surface, and the influence of flow field configurations on the flow distribution uniformity was firstly studied.

44 citations


Journal ArticleDOI
TL;DR: In this paper, the dynamics of gravity-driven displacement of a droplet on a grooved surface is studied using the Shan and Chen's pseudopotential multiphase lattice Boltzmann (LB) model allowing a high density ratio between the gas and liquid phases.

20 citations


Journal ArticleDOI
TL;DR: In this article, a coupled numerical model is employed to investigate the emission process of volatile organic compounds (VOCs) in the building material and chamber, and the model is numerically implemented by a multiscale strategy with the lattice Boltzmann method (LBM) being used to simulate pore-scale diffusion and finite volume method (FVM) for macroscopic transport.

19 citations



Posted Content
TL;DR: In this paper, the cavities behaviors for nucleation on roughened surface are numerically studied on the entire ebullition cycle based on a phase-change lattice Boltzmann method without introducing any artificial disturbances.
Abstract: Nucleate boiling heat transfer (NBHT) from enhanced structures is an effective way to dissipate high heat flux. In the present study, the cavities behaviours for nucleation on roughened surface are numerically studied on the entire ebullition cycle based on a phase-change lattice Boltzmann method without introducing any artificial disturbances. The adopted model is firstly validated with the Laplace law and the two phase coexistence curve, and then applied to investigate the effects of cavity structure on NBHT. The bubble departure diameter, departure frequency and total boiling heat flux of an ebullition cycle are also explored. It is demonstrated that the cavity widths and the cavity grooves show significant influence on the features of NBHT. Cavity with circular groove in the present research shows the best performance for NBHT in terms of the averaged heat flux and bubble release frequency. When a specific cavity is combined with other different cavities on roughened surfaces its nucleation process on different roughened surfaces may differ greatly.


Posted Content
TL;DR: In this paper, the effects of heterogeneity of mineral distribution and reaction rate on the rock dissolution process were investigated using a pore-scale reactive transport model based on the lattice Boltzmann method.
Abstract: Effects of heterogeneity of mineral distribution and reaction rate on the rock dissolution process are investigated using a pore-scale reactive transport model based on the lattice Boltzmann method. Coupled fluid flow, species transport, chemical reaction and solid structure alternation due to dissolution are simulated. Effects of mineral distributions and chemical heterogeneity on the dissolution behaviors and evolutions of hydrologic properties are studied under different reactive transport conditions. Simulation results show that the coupling between advection, diffusion and reaction as well as the mineralogical heterogeneity leads to complex reactive transport behaviors and complicated temporal evolutions of hydrologic properties including porosity, permeability and reactive surface. Diverse relationships between surface area and volume are predicted, which cannot be described by simple models such as the spherical-grain model. Porosity-permeability relationships also differ under different mineral distributions and reactive transport conditions. Simulation results indicate that it is extremely challenging to propose general relationships for hydrologic properties for dissolution of rocks with mineralogical heterogeneity, due to the complicated interactions between reactive transport and mineralogical heterogeneity.