[i] An inventory of air pollutant emissions in Asia in the year 2000 is developed to support atmospheric modeling and analysis of observations taken during the TRACE-P experiment funded by the National Aeronautics and Space Administration (NASA) and the ACE-Asia experiment funded by the National Science Foundation (NSF) and the National Oceanic and Atmospheric Administration (NOAA). Emissions are estimated for all major anthropogenic sources, including biomass burning, in 64 regions of Asia. We estimate total Asian emissions as follows: 34.3 Tg SO 2 , 26.8 Tg NO x , 9870 Tg CO 2 , 279 Tg CO, 107 Tg CH 4 , 52.2 Tg NMVOC, 2.54 Tg black carbon (BC), 10.4 Tg organic carbon (OC), and 27.5 Tg NH 3 . In addition, NMVOC are speciated into 19 subcategories according to functional groups and reactivity. Thus we are able to identify the major source regions and types for many of the significant gaseous and particle emissions that influence pollutant concentrations in the vicinity of the TRACE-P and ACE-Asia field measurements. Emissions in China dominate the signature of pollutant concentrations in this region, so special emphasis has been placed on the development of emission estimates for China. China's emissions are determined to be as follows: 20.4 Tg SO 2 , 11.4 Tg NO x , 3820 Tg CO 2 , 116 Tg CO, 38.4 Tg CH 4 , 17.4 Tg NMVOC, 1.05 Tg BC, 3.4 Tg OC, and 13.6 Tg NH 3 . Emissions are gridded at a variety of spatial resolutions from 1° × 1° to 30 s x 30 s, using the exact locations of large point sources and surrogate GIS distributions of urban and rural population, road networks, landcover, ship lanes, etc. The gridded emission estimates have been used as inputs to atmospheric simulation models and have proven to be generally robust in comparison with field observations, though there is reason to think that emissions of CO and possibly BC may be underestimated. Monthly emission estimates for China are developed for each species to aid TRACE-P and ACE-Asia data interpretation. During the observation period of March/ April, emissions are roughly at their average values (one twelfth of annual). Uncertainties in the emission estimates, measured as 95% confidence intervals, range from a low of ±16% for SO 2 to a high of ±450% for OC.

An inventory of gaseous and primary aerosol emissions in Asia in the year 2000 : NASA global tropospheric experiment transport and chemical evolution over the pacific (TRACE-P): Measurements and analysis (TRACEP1)

Surface functional groups of carbon-based adsorbents and their roles in the removal of heavy metals from aqueous solutions: A critical review.

Emerging natural and tailored materials for uranium-contaminated water treatment and environmental remediation

Thermochemical conversion of sewage sludge: A critical review

There is an increased global demand for activated carbon (AC) in application of water treatment and purification. Water pollutants that have exhibited a greater removal efficiency by AC included but not limited to heavy metals, pharmaceuticals, pesticides, natural organic matter, disinfection by-products, and microplastics. Granular activated carbon (GAC) is mostly used in aqueous solutions and adsorption columns for water treatment. Commercial AC is not only costly, but also obtained from non-renewable sources. This has prompted the search for alternative renewable materials for AC production. Biomass wastes present a great potential of such materials because of their availability and carbonaceous nature. This in turn can reduce on the adverse environmental effects caused by poor disposal of these wastes. The challenges associated with biomass waste based GAC are their low strength and attrition resistance which make them easily disintegrate under aqueous phase. This paper provides a comprehensive review on recent advances in production of biomass waste based GAC for water treatment and highlights future research directions. Production parameters such as granulation conditions, use of binders, carbonization, activation methods, and their effect on textural properties are discussed. Factors influencing the adsorption capacities of the derived GACs, adsorption models, adsorption mechanisms, and their regeneration potentials are reviewed. The literature reveals that biomass waste materials can produce GAC for use in water treatment with possibilities of being regenerated. Nonetheless, there is a need to explore 1) the effect of preparation pathways on the adsorptive properties of biomass derived GAC, 2) sustainable production of biomass derived GAC based on life cycle assessment and techno-economic analysis, and 3) adsorption mechanisms of GAC for removal of contaminants of emerging concerns such as microplastics and unregulated disinfection by-products.

Synthesis and application of Granular activated carbon from biomass waste materials for water treatment: A review

Facile functionalized of SBA-15 via a biomimetic coating and its application in efficient removal of uranium ions from aqueous solution.

Peroxymonosulfate (PMS)-based advanced oxidation processes (PMS-AOPs) as an efficient strategy for organic degradation are highly dependent on catalyst design and structured active sites. However, the identification of the active sites and their relationship with reaction mechanisms for organic degradation are not fully understood for a composite catalyst due to the complex structure. Herein, we developed a family of Co encapsulated in N-doped carbons (Co-PCN) with tailored types and contents of active sites via manipulated pyrolysis for PMS activation and ciprofloxacin (CIP) degradation, focusing on the correlation of active sites to generated reactive species and degradation routes of organics. The structure-function relationships between the different active sites in Co-PCN catalysts and reactive oxygen species (ROS), as well as bond breaking position of CIP, were revealed through regression analysis and density functional theory calculation. Co-Nx, O-C═O, C═O, graphitic N, and defects in Co-PCN stimulate the generation of 1O2 for oxidizing the C-C bond in the piperazine ring of CIP into C═O. The substitution of F by OH and hydroxylation of the piperazine ring might be induced by SO4•- and •OH, whose formation was affected by C-O, Co(0), Co-Nx, graphitic N, and defects. The findings provided new insights into reaction mechanisms in PMS-AOP systems and rational design of catalysts for ROS-oriented degradation of pollutants.

Li’an Hou

Papers

Facile functionalized of SBA-15 via a biomimetic coating and its application in efficient removal of uranium ions from aqueous solution.

Correlation of Active Sites to Generated Reactive Species and Degradation Routes of Organics in Peroxymonosulfate Activation by Co-Loaded Carbon.

A new function of spent activated carbon in BAC process: Removing heavy metals by ion exchange mechanism.

Air pollutant emissions from straw open burning: A case study in Tianjin

Supercritical water pyrolysis of sewage sludge